Carbohydrates Flashcards

(36 cards)

1
Q

Carbs

A

Most abundant organic molecule in nature

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2
Q

Function of Carbs

A

Energy, Cell membrane components for intercellular communication, and bacterial cell walls

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3
Q

6-C Structures prefer…

A

to be in an aromatic shape C6H1206

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4
Q

Carbs most common configuration in body…

A

D configuration

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5
Q

Racemases

A

enzymes that conver simple sugars between the L and D forms

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6
Q

Monosaccharides

A

Glyceraldehyde –> Arabinose –>Glucose & Mannose
Glyceraldehyde –> Lyxose –> Galactose
Dihydroxyacetone –> Ribulose –> Fructose

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7
Q

Isomers

A

Compounds with the same chemical formula

EX: Glucose, Fructose, Galactose

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8
Q

Epimers

A

Monosaccharide differ around a specific C.
EX: Galactose and glucose around C4
Mannose and Glucose around C2

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9
Q

Enantiomers

A

Non-super imposable mirror images. They are chiral.

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10
Q

Anomers

A

Cyclization creates an anomeric C. This creates an alpha and beta configuration. They can spontaneously switch forms which is called mutarotation. They help maintain the equilibrium in the body.
EX: alpha-D-glucopyranose: synthesizes glycogen
beta-D-glucopyranose: synthesizes cellulose

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11
Q

Glycosidic Bonds

A

Link monosaccharides. C1 Galactose, C4 Glucose

a config = a bond, B config = b bond

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12
Q

Glycosyltransferase

A

enzyme that forms Glycosidic Bonds

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13
Q

Lactose bond type

A

galactosyl- B (1-4) glucose

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14
Q

Asparagine & Sugar bond type

A

N-glycosidic bond (due to NH)

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15
Q

Serine & Sugar bond type

A

O-glycosidic bond (due to OH)

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16
Q

Disaccharide

A

2 Monosaccharides

17
Q

Oligosaccharide

A

3-12 Monosaccharides

18
Q

Polysaccharide

A

12 or more Monosaccharides

19
Q

Sucrose

A

Glucose and Fructose.
1a-2B bond
Broken down by Sucrase.

20
Q

Lactose

A

Galactose and Glucose.
1B-4 bond
Broken down by Lactase.

21
Q

Maltose

A

Glucose and Glucose
1a-4 bond.
Broken down by Maltase.

22
Q

Cellobiose

A

Glucose and Glucose

1B-4 bond.

23
Q

a-amylase

A

Breaks down Starches

24
Q

Hydrolysis

A

Glycosidase and H2O help to add OH on to seperate.

25
Starch Breakdown
- -> isomaltose (isomaltase or a-dextrinase) --> Glucose | - -> imaltose &imaltotriose (maltase) --> Glucose
26
Mouth Digestion
salivary a-amylase breaks starch into a-dextrins
27
Stomach Digestion
low pH stops salivary amylase - NO CARB DIGESTION
28
Small Intestine Digestion
Acid neutralized by bicarbonate secreted by pancrease. Pancreatic a-amylase continues. Final, enzymes synthesized by intestinal mucosal cells. Glucose, Galactose, & Fructose-->liver via portal circulation. Tri & oligosaccharides broken down in SI.
29
Lactase Deficiency
in the large intestine, lactose is broken down by bacteria into 2C metabolites, 3C metabolites and CO2
30
Portal Circulation
Small Intestine lactose uses B-galactosidase to go to galactose & glucose
31
Glycosaminoglycans (GAG)
Long unbranched repeating disaccharide units. | Compose: Catilage, Tendons, Skin, Blood vessels, Collagen, & Elastin.
32
Hyaluronate
Makes up the Synovial Fluid and Hyaluronic Acid
33
Chondriotin-4-sulfate & Chondroitin-6-sulfate
Makes up tendons and Ligaments
34
Dermatan sulfate & Keratan sulfate & Heparin
Makes up Connective Tissue
35
Proteoglycans
Found in the cartilage, they are the core protein that linear GAG chains covalently attach to. (Bottle Brush form) Common GAG: chondroitin sulfate & keratan sulfate
36
Glycopoteins
Proteins attached to oligosaccharides covalently. Branches instead of linear. Attaches to amino acids. Used in Cell phenomena: surface antigenicity, surface recognition & mucins in GI tract & urogenital tract.