Carbonyl Group Flashcards

1
Q

What is a carbonyl group

A

A carbonyl group is a compound that has a carbon connected to an oxygen by double bond. C= O

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2
Q

What is an aldehyde

A

An aldehyde is a carbonyl group that is connected to at least 1 hydrogen atom H(2)-C=O

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3
Q

What is a ketone

A

A ketone is a compound that contains a carbonyl group attached to at least 2 carbons.
C-C=O-C

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4
Q

Properties of aldehydes and ketones

A
  1. They are polar.
  2. Have a dipole-dipole attraction.
  3. Do not have hydrogen bonds.
  4. Only small aldehydes and ketones can be soluble the more carbons you add the less soluble they become.
  5. Their boiling points are lower than other alcohols.
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5
Q

What are the reactions of aldehydes and ketones

A

Controlled oxidation
Hydrogenation

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6
Q

What is a controlled oxidation reaction

A

Primary alcohol + oxygen = aldehyde + water

Secondary alcohol + oxygen = ketone + water

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7
Q

Hydrogenation

A

Aldehyde + H-H + catalyst/heat & pressure = primary alcohol

Ketone + H-H + catalyst/ heat & pressure = secondary alcohol

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8
Q

How to name an aldehyde

A

1- longest carbon chain including cabin of carbonyl group
2- drop “-e” add “-Al”

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9
Q

How to name a ketone

A

1- longest carbon chain including carbonyl group’s carbon
2- number the carbons so the carbonyl group can have the smallest possible carbon number
3- add “-one” instead of “-e”

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