Carboxylic acids

Question 1

Formula for Carbonyl

Answer 1

R-COOH

Question 2

Formula for acyl group

Answer 2

RCO- w/ hydroxyl attached

Question 3

Nucleophilic substitution reaction

Answer 3

Carboxylic Acids

Question 4

In this synthesis, oxidation of primary alcohols used __

Answer 4

Carboxylic acid; K2Cr2O7 and KMnO4

Question 5

Oxidation of methanol metabolized into _____ through ________ further metabolized into ______ through ________

Answer 5

acetyldehyde; CYP450 enzyme or alcohol dehydrogenase; acetic acid - aldehyde dehydrogenase

Question 6

Prevents accumulation of the toxic acetyldehyde metabolite

Answer 6

Oxidation of Ethanol

Question 7

Acetic acid in Reaction w/ Water and Indicator

Answer 7

Blue-Red Litmus ; pink soln.

Question 8

Stearic acid in Reaction w/ Water and Indicator

Answer 8

Blue-red; orange soln.

Question 9

reaction: release of proton/stability of conjugated base

Answer 9

Reaction w/ Water and Indicator

Question 10

Reaction w/ Water and Indicator is detected through __

Answer 10

Ph measurement ( Ph indicator/paper)

Question 11

Acetic Acid in Reaction with NaOH

Answer 11

soluble; cc soln

Question 12

Stearic Acid in Reaction with NaOH

Answer 12

insoluble; cc w/ white layer

Question 13

Reaction w/ strong bases

Answer 13

Water soluble salts (Neutralization) - Reaction with NaOH

Question 14

Acetic Acid in Reaction w/ Na2CO3

Answer 14

positive (Effervescence) ; no change after heating

Question 15

Reaction w/ weak bases

Answer 15

Water-soluble salt + CO2 - Reaction w/ Na2CO3

Question 16

function: differentiate Carboxylic acid from other weak acids

Answer 16

Reaction w/ Na2CO3

Question 17

Acetic acid in Esterification Reaction

Answer 17

Pear-like odor

Question 18

Benzoic acid in Esterification Reaction

Answer 18

Nutty-like Odor

Question 19

Reaction: alcohol reacts w/ carboxylic acid thru acid catalyst

Answer 19

Fischer Esterification - Esterification Reaction

Question 20

Fruity-like odor

Answer 20

Ester

Question 21

Acetic acid in Reaction w/ Neutral FeCl3

Answer 21

Turbid orange soln w/ reddish brown ppt

Question 22

Tartaric acid in Reaction w/ Neutral FeCl3

Answer 22

Turbid orange soln w/ reddish brown ppt

Question 23

Positive Result: Reaction w/ Neutral FeCl3

Answer 23

Reddish brown/ brick red ppt

Question 24

Reagent: Reaction w/ Neutral FeCl3

Answer 24

Neutral FeCl3

Question 25

Citric Acid in Special Test before and after heating

Answer 25

Green soln (before heating); Brown ppt (after heating)

Question 26

Tartaric Acid in Special Test before and after heating

Answer 26

Violet soln (before heating); Brown ppt (after heating)

Question 27

Tricarboxylic acid; no enan

Answer 27

Citric Acid

Question 28

Dicarboxylic acid; 2 enan

Answer 28

Tartaric acid

Question 29

Green soln in Special Test

Answer 29

alkaline manganate

Question 30

Brown ppt in Special Test

Answer 30

Manganese dioxide

Question 31

Ethyl acetate in Ferric Hydroxamate Test Preliminary test

Answer 31

pale yellow-green soln.

Question 32

Ethyl acetate in Ferric Hydroxamate Test Final test

Answer 32

Dark maroon soln.

Question 33

Ester formula

Answer 33

R1C=OOR

Question 34

Pleasant odor, used in perfume or flavoring

Answer 34

Ester

Question 35

function: Identify ester

Answer 35

Ferric Hydroxamate Test

Question 36

Acetic anhydride in Hydrolysis Reaction litmus ; Changes in soln.

Answer 36

Blue-Red Litmus; Evol of heat

Question 37

Acetamide in Hydrolysis Reaction litmus ; Changes in soln.

Answer 37

red-blue ; evol of gas

Question 38

Amides Formula

Answer 38

RC=ONH2

Question 39

W/ 2 acryl group (R-C=O)

Answer 39

Acid anhydrides

Question 40

Hydrolyzed into 2 moo acetic acid

Answer 40

Acetic anhydride

Question 41

Carboxylate salt and free ammonia

Answer 41

Acetamide