Ceramics 1 Flashcards
(30 cards)
Types of Ceramics
<p>Ceramic
Glasses
Glass-ceramics</p>
Ceramic definition
<p>Refractory polycrystalline compound
| </p>
Ceramic properties
<p>Usually inorganic Highly inert Hard and brittle High compressive strength, low tensile Generally good insulators Good tribological props. </p>
Natural ceramic composites
<p>Bones, teeth, shells
| Hard tissues</p>
Ceramic structures
<p>Crystalline
Semi-crystalline
Amorphous</p>
Ceramic examples<
<p>Alumina Bioglass Ca Phosphates Hydroxyapatite Ca3 Phosphate</p>
Bioactivity
<p>allows material to form a bond with living tissue
| stimulates healing by responding as if it were a natural tissue</p>
Bioinert
<p>Not bonded
Relative movement (articulation)
Fibrous layer</p>
Porous inert
<p>Tissue ingrowth
Fixation
Reduced movement</p>
Surface reactive
<p>Chemical bonds
Slow degradation
Induces bone formation</p>
Resorb-able
<p>Degrades</p>
Ceramic processing
<p>Cast or Plasma spraying Liquid-phase sintering Solid-state sintering Glass-ceramic Glass</p>
Ceramic Strengthening
For ceramics: to prevent fracture or inhibit crack propagation
They fracture easily under tension
Polishing
Etch and Fire polish
Smaller grains
Eliminate flaws
Annealing
eliminate residual stress
Ion exchange
Intro of bigger cations within structure
Porosity
3% porosity = 10x decrease in strength
Alumina (Type 1)
Aluminum oxides Nearly inert crystalline ceramic Bioinert Small grain and porosity = higher strength Stress shielding problems High hardness, low wear
Alumina Applications
Orthopedics (heads, bone screws/plates
Dental crowns and bridges
Type 2
Structural bridge or scaffold for bone formation
Type 3
Bioactive glasses and glass-ceramics
Direct chemical bonding
Glass (3)
inorganic melt cooled to solid w/o crystallization
Amorphous solid
Brittle
Glass-ceramic
Polycrystalline solid
Stimulatory effect on bone
Ca-Phosphate (3,4)
Naturally occurring (bone) Poor mechanical behavior Porosity determines: Tensile/Compressive strength and fatigue resistance