Ch 4 - Compounds and Stoichiometry Flashcards

1
Q

What are compounds?

A

substances composed of 2+ elements in a fixed proportion

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2
Q

What is the difference between molecular weight and molecular mass?

A
  • weight: the mass (in amu) of the constituent atoms in a compound as indicated by the molecular formula
  • mass: mass of one mle (Avagadro’s number) of a compound; usually measured in grams per mole
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3
Q

What gram equivalent weight?

A

a measure of the mass of a substance that can donate one equivalent of the species of interest

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4
Q

What is normality?

A

the ratio of equivalent per liter; it is related to molarity by multiplying the molarity by the number of equivalents present per mole of the compound

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5
Q

What are equivalents?

A

moles of the species of interest; most often seen in acid-base chemistry and redox reactions

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6
Q

What is the law of constant composition?

A

any pure sample of a compound will contain the same elements in the same mass ratio

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7
Q

What is the difference between the empirical formula and the molecular formula?

A
  • empirical: smallest whole number ratio of the elements in the compound
  • molecular: either the same as or a multiple of the empirical formula; it gives the exact number of atoms of each element in a compound
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8
Q

How do you calculate the percent composition by mass?

A

determine the mass of the individual element and divide by the molar mass of the compound

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9
Q

When do combination reactions occur?

A

when 2+ reactants combine to form one product

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10
Q

When do decomposition reactions occur?

A

when one reactant is chemically broken down into 2+ products

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11
Q

When do combustion reactions occur?

A

when a fuel and an oxidant (typically oxygen) react, foring the products water and carbon dioxide

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12
Q

When do displacement reactions occur?

A

when 1+ atoms or ions of one compound are replaced with one or more atoms or ions of another compound

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13
Q

What is the difference between single- and double-displacement reactions?

A
  • single: occur when elements from 1 compound is replaced with another element
  • double: occur when elements from 2 different compounds trade places with each other to form 2 new compounds
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14
Q

What are neutralization reactions?

A

an acid reacts with a base to form a salt (and usually water)

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15
Q

What is the difference between limiting and excess reagents?

A
  • limiting: reactant that will be consumed first in a chemical reaction
  • excess: other reactant
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16
Q

What is theoretical yield, actual yield, and percent yield?

A
  • theoretical: amount of a product generated if all the limiting reactant is consumed with no side reactions
  • actual: typically lower than theoretical
  • percent: actual/theoretical x 100%
17
Q

What is the nomenclature for ionic compounds?

A
  • charge indicated by roman numerals
  • monatomic ions: -ide
  • polyatomic ions: -ite/-iate
18
Q

What are the formulas for ammonium, acetate, cyanide, permanganate, thiocyanate, chromate, dichromate, and borate?

A

NH4+, CH3COO-, CN-, MnO4-, SCN-, CrO4-2, C2O7-2, BO3-3

19
Q

What are the rules for oxidation states?

A
  • correlates to charge
  • H +1, O -2, F -1
  • sum equal to charge of compound
20
Q

What are electrolytes?

A
  • solutes that enable solutions to carry currents
  • ionic compounds are good because they dissolve most readily
  • non polar covalent compounds are weakest because they do not form current carrying ions
21
Q

Formula for acetone?

A

C3H6o

22
Q

Formula for ethanol?

A

C2H5OH

23
Q

Formula for propane?

A

C3H8

24
Q

Formula for methanol?

A

CH3OH