Ch. 8 Quantum Mechanics And Periodic Trends Flashcards

(56 cards)

0
Q

The theory which allows us to determine the probability of finding an electron at a particular place in the Atom

A

Quantum mechanics

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1
Q

Modern atomic theory is referred to as

A

Quantum mechanics

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2
Q

It is impossible to know both the speed and location of an electron at the same time

A

Heisenberg uncertainty principle

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3
Q

Particles that are involved in light

A

Photons

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4
Q

What is the principal quantum number

A

Describes the main energy level of the electron in its distance from the nucleus

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5
Q

How do you calculate the principal quantum number

A

2n^2

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6
Q

What levels to the electrons occupy

A

The lowest energy levels which are the closest to the nucleus

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7
Q

Azimuthal quantum number

A

Describes the sub level the electron is in

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8
Q

List the sub levels in order from least energetic to most energetic

A

S
p
D
F

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9
Q

Azimuthal quantum number

A

Also describes the shape of the electron cloud

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10
Q

Region of space in which an electron of a particular energy might be found

A

Electron cloud

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11
Q

What does the S as azimuthal quantum number look like

A

Sphere

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12
Q

What does the P look like

A

Propeller

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13
Q

What does the d look like

A

Daisy

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14
Q

What does the f look like

A

Too funky to draw

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15
Q

The shape of the space where there is a high probability of finding electrons

A

Orbital

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16
Q

Magnetic quantum number (m)

A

Describes the orbitals orientation in space

Represents the number of ways in which you can position an electron cloud

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17
Q

The space occupied by a pair of electrons

A

Orbital

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18
Q

When placing electrons into orbitals within a sub level place them in orbitals one at a time before doubling up

A

Hund’s role of maximum multiplicity

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19
Q

Spin quantum number (s)

A

Represents the direction of the electron spin

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20
Q

Where does an electron spin and how

A

Electron spins on its axis clockwise and counterclockwise

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21
Q

No two electrons in the same atom can have the same set of four quantum numbers

A

Pauli exclusion principle

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22
Q

Having the same energy

23
Q

Electrons will remain unpaired in a given orbital until orbitals of the same sublet will have at least one electron

A

Hund’s rule

24
What sublevels overlap
The 4s and 3d
25
Went to the overlaps become more frequent
As electrons are placed in n=5 and beyond
26
How are energy levels spaced
They are not equally spaced as you get further from the nucleus energy levels get closer together and overlap
27
A property that can be predicted based on an elements location on the periodic table
Periodic trend
28
The distance from the center of the nucleus to the edge of the electron cloud
Atomic radius
29
Why do scientists use a covalent radius or half the distance between the nuclei of two bonded Atoms
Because an electron clouds edge is difficult to define
30
What is an Angstrom
1×10 to the -10 m
31
What is the trend for atomic radius
Larger as you go down the column and smaller as you go to the right in the row
32
What is the atomic radius get larger as you go down the column
Because each step down adds an entirely new main energy level making the Atoms larger
33
What is the atomic radius get smaller as you go to the right in the row
Because each step right adds a proton and an electron yet the Atoms do not get larger because they are added to existing main energy levels the added electrons are not farther from the nucleus and the effective nuclear charge is greater
34
Attraction that pulls the electron cloud in
Effective nuclear charge
35
Pull that an electron feels from the nucleus
Effective nuclear charge
36
The larger the effective nuclear charge
The tighter the electron cloud gets pulled in
37
Why don't we see the effective nuclear charge occur when going down the column
As more main energy levels are added to the Atoms the inner layers of electrons shield the outer electrons from the nucleus
38
The energy required to remove an electron from an Atom
Ionization energy
39
What is the relationship between ionization energy and atomic radius
Inversely proportional
40
Ionization energy is always
Endothermic | Energy is added to the atom to remove the electron
41
A measure of an atom's desire for electrons in a chemical bond
Electronegativity
42
What element has the highest electronegativity in what is the value
Fluorine the value is 4
43
Which elements or electron dinners and have low electronegativities
Metals
44
Which elements are electronic accepter's and have high electronegativities
Nonmetals
45
Best electron dinners and the largest
Metals
46
Best electron takers and are the smallest
Nonmetals
47
No electronegativities
Noble gases
48
All of the ions with the same electron configuration
Isoelectronic series
49
Goes from regular element to negative ion
Ion is bigger less effective nuclear charge
50
Goes from regular element to Positive ion
Ion is smaller
51
Why don't elements change in an isoelectronic series
Because protons determine the element
52
Equations needed to calculate the energy involved in an electron transition
Delta E equals RH times the quantity one over ni squared -1 over nf squared E equals HV C equals V upside down y
53
Number of cycles that pass in a certain amount of time
Frequency
54
V
Frequency
55
Upside down y
Wavelength