Ch1-6 Flashcards
(33 cards)
Intensive property
Boiling point, freezing point, density, temperature, pressure
Extensive property
Mass, volumes, moles
Separating mixtures
Manually, magnetism, dissolving, filtration, evaporation, crystallization, distillation, chromatography
State function
Property whose value does not depend on path
Mass, pressure, density, energy, temperature, volume, enthalpy, entropy, Gibbs, chemical composition
Celsius and F
C = 5/9 (F -32)
Kelvin
K = C+ 273
Hess’s Law
Measure of enthalpy change of chemical reaction
+H endothermic energy in
-H exothermic energy out
Joule : 1 cal = J….
Specific heat capacity of water
4.184 J
Q = ?
s x m x delta T
S= specific heat capacity
M = mass in grams
T = C
Entropy S =
Delta S= S final - S initial
J/mol K
Gibbs free energy
G =H - TS
-G = spontaneous
+G = non spontaneous
E(cell) =
E redux - E oxid
More + more energy u get out
First law thermometer
Energy cannot be created or destroyed
2nd law of thermos
Not all energy can be used
Disorder tends to increase over time
Intermolecular forces
Hydrogen bonds
Ion-dipole
Dipole dipole
Dipole induced dipole
London dispersion forces
1 atm ….
14.7 psi =1.0135 bars 760 mmHG = 760 torr at seas level
Mole
6.023x10^23
Boyles law PV
P1 x V1 = P2 x V2
Charles law V/T
Gases heated the volume will increase with pressure held constant
Gay-Lissacs law P/T
Pressure increases as temperature increases if volume held constant
Video gas law
PV =NRT
R= .0821 L atm / mol K
Van der waals equation
P + an^2/V2) + (V -nb) = nRT
a= attraction
b= volume of gas molecules
n= number of moles of gas
Molarity M
Moles solute / L of solution
molality m
Moles solutes / kg solvent