Ch1-6 Flashcards

(33 cards)

1
Q

Intensive property

A

Boiling point, freezing point, density, temperature, pressure

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2
Q

Extensive property

A

Mass, volumes, moles

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3
Q

Separating mixtures

A

Manually, magnetism, dissolving, filtration, evaporation, crystallization, distillation, chromatography

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4
Q

State function

A

Property whose value does not depend on path

Mass, pressure, density, energy, temperature, volume, enthalpy, entropy, Gibbs, chemical composition

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5
Q

Celsius and F

A

C = 5/9 (F -32)

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6
Q

Kelvin

A

K = C+ 273

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7
Q

Hess’s Law

A

Measure of enthalpy change of chemical reaction

+H endothermic energy in
-H exothermic energy out

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8
Q

Joule : 1 cal = J….

Specific heat capacity of water

A

4.184 J

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9
Q

Q = ?

A

s x m x delta T
S= specific heat capacity
M = mass in grams
T = C

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10
Q

Entropy S =

A

Delta S= S final - S initial

J/mol K

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11
Q

Gibbs free energy

A

G =H - TS

-G = spontaneous
+G = non spontaneous

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12
Q

E(cell) =

A

E redux - E oxid

More + more energy u get out

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13
Q

First law thermometer

A

Energy cannot be created or destroyed

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14
Q

2nd law of thermos

A

Not all energy can be used
Disorder tends to increase over time

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15
Q

Intermolecular forces

A

Hydrogen bonds
Ion-dipole
Dipole dipole
Dipole induced dipole
London dispersion forces

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16
Q

1 atm ….

A

14.7 psi =1.0135 bars 760 mmHG = 760 torr at seas level

17
Q

Mole

18
Q

Boyles law PV

A

P1 x V1 = P2 x V2

19
Q

Charles law V/T

A

Gases heated the volume will increase with pressure held constant

20
Q

Gay-Lissacs law P/T

A

Pressure increases as temperature increases if volume held constant

21
Q

Video gas law

A

PV =NRT
R= .0821 L atm / mol K

22
Q

Van der waals equation

A

P + an^2/V2) + (V -nb) = nRT
a= attraction
b= volume of gas molecules
n= number of moles of gas

23
Q

Molarity M

A

Moles solute / L of solution

24
Q

molality m

A

Moles solutes / kg solvent

25
Mass percent
Mass of solute / mass solution. X 100
26
Soluble
Group 1 elements Ammonium NH4. + Nitrates NO3- Chlorides Cl- Not ag, hg, cl, pb Sulfates SO4. -2
27
Insoluble
Carbonates CO3 -2 Hydroxide OH- Sulfides S -2
28
Henry’s law
How u force gas carbonation into soda
29
Dilution of solutions
M1 x V1 = M2 x V2
30
Colligative property
Depends on the number of sultry particles not type Vapor pressure lowering Boiling point elevation Freezing point depression Osmotic pressure
31
Freezing point depression
Delta T = -iKfm I = number of ions dissolves Kf = constant m = molality = molar mass = solute moles/kg solvent
32
Raoults law
P sol = P1X1 + P2X2 etc P1 = pressure of or P knot X1 = mole fraction of this part
33