CH3 Bonding Flashcards

1
Q

What is ionic bonding

A

Strong electrostatic forces of attraction between oppositely charged ions held in a lattice

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2
Q

Example of ionically bonded substance

A

NaCl - Sodium chloride

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3
Q

How high are ionically bonded substances BP and MP - why

A

High - Takes lots of energy to break strong electrostatic forces of attraction between oppositely charged ions

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4
Q

Do ionic compounds conduct electricity - why

A

Yes - when molten or in solution as the ions are free to move and carry charge

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5
Q

What is simple molecular covalent bonding

A

Strong covalent bonds between atoms, weak van der Waals forces of attraction between molecules

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6
Q

Are there any lone electrons in simple covalent bonding

A

No - they are all involved in bonding

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7
Q

Can simple molecular molecules conduct electricity - why

A

No - all electrons used in bonding and arent free to move

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8
Q

Do simple molecular substances have high or low MP and BP - why

A

Low - weak van der Waals forces of attraction between molecules that dont take much energy to overcome

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9
Q

Descrive macromolecular covalent bonding

A

Lattice of many atoms held together by strong covalent bonds

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10
Q

Do macromolecular covalently bonded substances have high or low MP and BP - why

A

High - takes a lot of energy to overcome many strong covalent bonds

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11
Q

Do substances with macromolecular covalent bonds conduct electricity

A

Most dont as all electrons are used in bonding

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12
Q

Describe structure of diamond

A

3D tetrahedral structure of C atoms, with each C atom bonded to 4 others

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13
Q

Describe structure of graphite

A

Macromolecular covalent - each C atom only bonded to 3 other C atoms
Weak van der Waals forces between layers so layers can slide over each other
Conducts electricity due to 1 delocalised electron from each C atom

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14
Q

Describe metallic bonding

A

Lattice of positive metal ions strongly attracted to a sea of delocalised electrons
Malleable as layers can slide over each other

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15
Q

Do metallic compounds have high or low BP and MP - why

A

High - strong forces of attraction between positive metal ions and negatively charged sea of delocalised electrons

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16
Q

Do metallic compounds conduct electricity - why

A

Yes - delocalised electrons can move throughout the metal to carry charge

17
Q

How does strength of metallic bonds change across periodic table - why

A

Increases - higher MP and BP
Stronger charge on metal ions
More delocalised electrons per ion
Stronger force of attraction

18
Q

Define electronegativity

A

The ability of an atom to attract the pair of electrons in a covalent bond

19
Q

What affects electronegativity

A

Nuclear charge
Atomic radius
Electron shielding

20
Q

Most electronegative element

A

Fluorine - largest nuclear charge for its electron shielding, small atomic radius

21
Q

How do you get non-polar bonds

A

Both bonding elements have the same electronegativities

22
Q

When do you get a polar bond

A

Bonding atoms have different electronegativities

23
Q

Strongest type of inter-molecular force

A

Hydrogen bonding

24
Q

Weakest type of inter-molecular force

A

van der Waals forces

25
Describe van der Waals' forces of attraction
Temporary dipoles are created by the random movement of electrons Induces dipole in neighbouring molecule
26
Are van der Waals forces greater in smaller or larger molecules
Larger - more electrons present
27
Describe permanent dipole-dipole attraction
Some molecules with polar bonds have permanent dipoles | Forces of attraction between those dipoles and those of neighbouring molecules
28
Why is ice less dense than liquid water
Liquid - hydrogen bonds constantly break and reform as molecules move about Ice - Hydrogen bonds hold molecules in fixed position making them further apart from each other than in liquid water
29
Dative covalent bond
Formed when an electron deficient atom/ion accepts a lone pair of electrons from another atom/ion with a free lone pair of electrons
30
What does shape of molecules depend on
Number of electrons in the valence shell of the central atom | Number of these electrons which are in bonded or lone pairs
31
What does the Electron Pair Repulsion Theory state
Electron pairs will take up positions as far away from each other as possible, minimise the repulsive forces between them
32
Which experience the most repulsion; Lone pair - Lone pair Lone pair - Bonded pair Bonded pair - Bonded pair
LP - LP = strongest repulsion LP - BP = middlle repulsion BP - BP = weakest repulsion
33
Shape and bond angle of a shape with 2 bonded pairs and 0 lone pairs
Linear | 180 degrees
34
Shape and bond angle of shape with 3 bonding pairs and 0 lone pairs
Trigonal planar | 120 degrees
35
Shape and bond angle of shape with 4 bonded pairs and 0 lone pairs
Tetrahedral | 109.5 degrees
36
Shape and bond angle in a shape with 5 bonded pairs and 0 lone pairs
Trigonal bipyramid | 90 and 120 degrees
37
Shape and bond angles of shape with 6 bonded pairs and 0 lone pairs
Octohedral | 90 degrees