CH6-7 Flashcards

(35 cards)

1
Q

What is a solution?

A

A homogeneous mixture of two or more substances

Solutions consist of at least one solute and one solvent.

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2
Q

Define solute.

A

The component of a solution that is present in lesser quantity

Examples include salt in saltwater.

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3
Q

Define solvent.

A

The solution component present in the largest quantity

Water is the most common solvent.

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4
Q

What is an aqueous solution?

A

A solution where the solvent is water

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5
Q

What are electrolytes?

A

Formed from solutes that are soluble ionic compounds

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6
Q

What is solubility?

A

How much of a particular solute can dissolve in a certain solvent at a specified temperature

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7
Q

What factors affect solubility?

A
  • Polarity of solute and solvent
  • Temperature
  • Pressure

The more different the polarities, the lower the solubility.

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8
Q

What is a saturated solution?

A

A solution that contains all the solute that can be dissolved at a particular temperature

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9
Q

What is a supersaturated solution?

A

Contains more solute than can be dissolved at the current temperature

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10
Q

What occurs at equilibrium in a saturated solution?

A

The rates of dissolution and precipitation are equal

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11
Q

Define concentration.

A

Amount of solute dissolved in a given amount of solution

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12
Q

How do you calculate mass/volume percent?

A

Mass/Volume Percent = (mass of solute in grams / volume of solution in milliliters) × 100

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13
Q

What is molarity?

A

The number of moles of solute per liter of solution

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14
Q

What are colligative properties?

A

Properties of solutions that depend on the concentration of solute particles, rather than the identity of the solute

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15
Q

What is Raoult’s law?

A

When a nonvolatile solute is added to a solvent, vapor pressure of the solvent decreases in proportion to the concentration of the solute

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16
Q

What is boiling point elevation?

A

The increase in boiling temperature necessary to raise the vapor pressure to atmospheric pressure when a solute is present

17
Q

Define freezing point depression.

A

The interference of solute molecules with the rate at which liquid water molecules associate to form the solid state

18
Q

What is osmotic pressure?

A

The amount of pressure required to stop the flow across a semipermeable membrane

19
Q

Define isotonic solutions.

A

Solutions with identical osmotic pressures and no osmotic pressure difference across the cell membrane

20
Q

What defines a hypertonic solution?

A

Solute concentration of fluid surrounding cells is higher than inside, causing water to flow out and cell collapse

21
Q

What defines a hypotonic solution?

A

Solute concentration of fluid surrounding cells is lower, causing water to flow into the cell and rupture it

22
Q

What is an exothermic reaction?

A

A reaction that releases energy to the surroundings

23
Q

What is an endothermic reaction?

A

A reaction that absorbs energy from the surroundings

24
Q

Define enthalpy.

A

Energy content released during bond formation or required to break chemical bonds

25
What does ΔH represent?
The energy difference between the products and reactants of a chemical reaction
26
What is entropy?
The measure of the statistical distribution of energy in a system
27
What does ΔG indicate?
Determines if a reaction will occur and predicts reaction spontaneity
28
What is calorimetry?
The experimental measurement of heat energy changes in a chemical reaction
29
Define activation energy (Ea).
The minimum amount of energy required to initiate a chemical reaction
30
What factors influence reaction rate?
* Structure of reactants * Temperature * Concentration * Presence of a catalyst ## Footnote More collisions lead to faster reactions.
31
What is a dynamic equilibrium?
A situation where the rate of the forward process in a reversible reaction is balanced by the rate of the reverse process
32
What does LeChatelier’s Principle state?
If a stress is placed on a system at equilibrium, the system will respond to minimize that stress
33
What effect does increased temperature have on an exothermic reaction?
Shifts equilibrium left, favoring the reactants
34
What effect does increased temperature have on an endothermic reaction?
Shifts equilibrium right, favoring the products
35
What is the effect of pressure on equilibrium?
Only significantly affects gases; increases equilibrium towards fewer gas molecules