Chap 24-26 Flashcards by Nydia Dixon

Q

Amines (& Nomenclature)

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Q

Basicity of Amines

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Q

Synthesis of Amide: From alkyl halide via nitrile (reduction of nitrile)

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Q

Synthesis of Amide: From carboxylic acid via amide

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Q

Synthesis of Amide: Reduction of nitrobenzene

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Q

Synthesis of Amide: Alkylation of ammonia and amine

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Q

Synthesis of Amide: From alkyl azide

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Q

Synthesis of Amide: Gabriel Synthesis

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Q

Synthesis of Amide: (1, 2 or 3 degree amines) Reductive amination

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Q

Synthesis of Amide: (1, 2 or 3 degree amines) Reductive amination (one-pot)

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Q

Reaction of amide: Hoffman elimination

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Q

Reaction of amide: oxidation of nitrous acid

A

Can’t do with 1 degree

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Q

Reaction of Aryldiazonium Ion

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Q

Diazo Coupling reaction

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Q

Carbohydrates (& Nomenclature)

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Q

Carbohydrates: D vs. L

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Q

Carbohydrates: Anomers

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Q

Rxn of monosacchride: Ester formation

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Q

Rxn of monosacchride: Ether formation

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Q

Rxn of monosacchride: Glycoside formation

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Q

Rxn of monosacchride: Reduction

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Q

Rxn of monosacchride: Bromine Water Oxidation

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Q

Rxn of monosacchride: Nitric Acid Oxidation

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Q

Rxn of monosacchride: Kiliani-Fischer Synthesis (Chain lenthening rxn)

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Rxn of monosacchride: Wohl Degradation (Chain shortening rxn)

Amino acid

pH of amino acids

Amino acid: Isoelectric Point

Amino acid: Henderson Hasselbach equation

Synthesis of Amino acid: Dehydration

Synthesis of Amino acid: SN2 Mechanism

Synthesis of Amino acid: From acetamido malonate ester

Synthesis of Amino acid: Streker method

Seperating D & L amino acids (resolution)

Amino Acids: Building Proteins