chap 28 organic synthesis pathways Flashcards by Hanna Molalign

Q

alkene to haloalkane

A

hydrogen halide

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Q

haloalkane to nitrile

A

NaCN

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Q

nitrile to amine

A

H2/Ni catalyst
reduction

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Q

haloalkane to amine

A

NH3 and ethanol

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Q

haloalkane to primary alcohol

A

aq NaOH

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Q

primary alcohol to aldehyde

A

heat with distil
K2Cr2O7/H2SO4
Oxidation

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Q

aldehyde to COOH

A

K2Cr2O7/H2SO4
Oxidation
heat with reflux

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Q

COOH to acyl chloride

A

SOCl3

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Q

Acyl chloride to COOH

A

H2O

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Q

aldehyde to primary alcohol

A

NaBH4/H2O
reduction

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Q

primary alcohol to haloalkane

A

NaOH
H2SO4

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Q

primary alcohol to alkene

A

H2SO4

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Q

alkene to primary alcohol

A

H3PO4/H20
Hydration

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Q

aldehyde to hydroxynitrile

A

nucleophilic addition
NaCN H+

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Q

nitrile to COOH

A

hydrolysis
H20/HCl

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Q

primary alcohol to ester

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A

COOH and H2SO4

Q

COOH to ester

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A

alcohol
H2SO4

Q

Ester to sodium salt of COOH & OH

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A

NaOH
alkaline hydrolysis

Q

acyl chloride to ester

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A

alcohol

Q

ester to COOH

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A

dilute acid hydrolysis

Q

acyl chloride to primary amide

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A

NH3

Q

acyl chloride to secondary amine

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A

primary amine