Chapter 1 Flashcards

(33 cards)

1
Q

Atomic number

A

Z, number of protons

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2
Q

Mass number

A

A, sum of protons and neutrons

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3
Q

isotopes

A

same atomic number, different masses (different number of neutrons)

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4
Q

atomic mass

A

equal to mass number in amu

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5
Q

atomic weight

A

weighted average of isotopes

mass of 1 mole in grams

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6
Q

avadagros number

A

1 mole, number of things

6.022 x 10 ^23

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7
Q

Rutherford

A

atoms have dense, positive nucleus

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8
Q

quanta

A

bundles of energy emitted as electromagnetic radiation from matter

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9
Q

energy of quanta equation

A

E= hf

h is constant= 6.626 x 10^ -34

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10
Q

Bohr

A

atoms is central protons with electrons in orbit

force is electrostatics between protons and electrons

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11
Q

angular momentum equation

A

L= nH/2pi

n is principal quantum number

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12
Q

energy of electron equation

A

E= -RH/ n squared

R= 2.18 x 10^-18 J/e

energy increases farther out from nucleus

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13
Q

atomic emission energy

A

E= hc/ wavelength

c= 3x 10 ^8

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14
Q

line spectrum

A

emit fluorescence when moving from excited to ground

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15
Q

Energy level tansition

A

E= Hc/ wavelength
= Rh (1/ni^2 - 1/nf^2

energy emitted is energy difference between initial and final energy

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16
Q

absorption spectra

A

from exciting electrons at specific wavelength

17
Q

orbitals

A

electrons move rapidly around these regions of space

18
Q

heisenberg uncertainty principle

A

cant determine electron momentum and position together

19
Q

pauli exclusion

A

no 2 electrons can have same set of 4 quantum numbers

20
Q

quantum numbers

21
Q

principal quantum number

A

n, positive integer, larger means higher energy level and shell radius

22
Q

max electrons in shell

23
Q

azimuthal quantum number

A

l, angular momentum, shape and number of subshells

from 0 to n-1

0=s 1=p 2=d 3=f

24
Q

max number of electrons in subshell

25
magnetic quantum number
ml, where electrons are likely found, orbital holds 2 electrons from -l to l s is sphere and p is dumbbell
26
spin quantum number
ms, - or + 1/2 orbitals have paired spin
27
configuration
pattern in which subshells are filled first number is n letter is subshell superscript is number of electrons in subshell
28
afbau principle
electrons fill low to high energy subshell and fill completely before next
29
N+ L rule
shows rank of highest energy
30
hunds rule
fill orbitals to have max number of half filled orbitals with parallel spin if all have full- its lower E and stable
31
exceptions to configurations
chromium has s1,d5 copper has s1 d10
32
paramagnetic
magnetic field causes parallel spins in unpaired electrons, causes align and attraction to magnetic field
33
diamagnetic
only paired electrons, slightly repelled by magnetic field