Chapter 1: Atomic Structure Flashcards
(24 cards)
Subatomic Particles:
Three types are: protons, neutrons, & electrons.
Protons:
This is found in the nucleus of an atom, has a mass of 1 atomic mass unit (amu), is positive, and is the same as the atomic number. • Aka Atomic Number. • Equals to the number of electrons.
Neutrons:
This is found in the nucleus of an atom, is neutral, has no charge, and has a mass larger than a proton.
Atomic Mass/Mass Number:
This is the sum of the protons and neutrons in the atom’s nucleus. • Constant for a given element, and is on the periodic table. • Example: Oxygen has 16
Atomic Weight:
This is similar to the mass number, but includes isotopes. • It’s the weighted average of different isotopes.
Isotopes:
This are atoms that share an atomic number but have different mass numbers.
Electrons:
These move through spaces surrounding the nucleus, has an equal but negative charge to a proton, and has a mass of 1/2000 of a proton.
Distance of electrons in the nucleus: Closer to the nucleus = Further from the nucleus =
• If the electron is closer to the nucleus, it has a low energy level. • But if they are further from the nucleus, then it has a high energy level.
Valence Electrons:
Electrons that are furthest from the nucleus. § They have the strongest interactions with the surrounding environment and the weakest with the nucleus. § It can determine the reactivity of an atom. Are on the peroidic table. They are the group numbers. So Hydrogen, lithium and more are in group 1, they will have 1 valence electron. Oxygen, sulfur, etc are in group 16 and they will have 6 valence electrons.
Cations: Anions:
Cations: Positively charged atom. Anions: Negatively charged atom.
Avogadro’s Number:
Equal to a “mole”. It’s value is 6.02x1023.
A mole is a number of things.
Quantum Mechanical model:
Posits that electrons do not travel in defined orbit but rather are localized in orbitals.
Orbitals:
This is a region of space around the nucleus defined by the probability of finding an electron in that region of space.
Heisenberg uncertainty principle:
States that it is impossible to know both an electrons position and its momentum exactly at the same time.
Four quantum numbers:
Includes:
Principal Quantum Number:
Azimuthal Quantum Number:
Magnetic Quantum Number
Spin Quantum Number:
Principal Quantum Number: (n)
This quantum number describes the average energy of a shell.
Azimuthal Quantum Number: (l);
This quantum number describes the subshells within a given principal energy level. (s,d,p,f)
Magnetic Quantum Number: (Ml);
This quantum number specifies the particular orbital within a subshell where an electron is likely to be found at a given moment in time.
Spin Quantum Number: (Ms);
This quantum number indicates the spin orientation of an electron in an orbital.
Electron Configuration:
The measure of the ability of an atom to attract the electrons in a bond.
It uses spectroscopic notation, where the first number is the principle energy level, and the letter designates the subshell, and the superscript gives the number of electrons in that subshell.
Hund’s Rule:
Electrons fill orbitals according to this rule.
It states that subshells with multiple orbitals (p,d, and f) fill electrons so that every orbital in a subshell gets one electron before any of them gets a second.
Electron Configuration of Negatively Charged Ions (Anions):
These will have an additional electrons.
Example: F (Fluroine) This is up to 2p.
So fluroine will be: 1s22s22p5, but
F- = 1s22s22p6
Electron Configuration of Positively charged ions (Cations):
In this, electrons will be removed from the subshells with the highest values for n first.
Example:
Zn (Zinc) = 1s22s22p63s23p64s23d10
but Zn2+ = 1s22s22p63s23p64s03d10
What is the electron configuration of Magnesium (Mg)?
It is located in the 3S section. So it will be 1s22s22p63s2.