Chapter 1 Review: Energy and Reaction Rate ✓ Flashcards

(38 cards)

1
Q

What is energy?

A

Energy is the capacity to do work or cause change

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2
Q

What is energy measured in?

A

Joules (J)

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3
Q

What are some forms of energy?

A

-Heat
-Chemical
-Electrical
-Light
-Kinetic
-Potential

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4
Q

What is a system?

A

The reaction mixture

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5
Q

What is the surroundings?

A

The object holding the mixture and anything else around it

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6
Q

What is the Law of Conservation?

A

Energy is neither created nor destroyed. Energy changes from one form of energy into another form

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7
Q

What is enthalpy?

A

A measure of the energy present in a substance

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8
Q

What happens during a chemical change in terms of the bonds?

A

Some bones are broken and new ones are formed which causes a change in the amount of stored chemical potential energy

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9
Q

What is enthalpy change?

A

The amount of heat energy transferred during a chemical reaction at constant pressure

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10
Q

How to find enthalpy change?

A

enthalpy of products - enthalpy of reactants

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11
Q

What is an exothermic reaction and give an example of one.

A

Reactions that lose heat to the surroundings (e.g. combustion

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12
Q

Is the value of enthalpy change negative or positive for an exothermic reaction?

A

Negative because enthalpy decreases during the course of the reaction

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13
Q

Why do exothermic systems feel hot?

A

Exothermic systems feel hot because energy is released to the surroundings as bonds form. This causes a decrease in enthalpy (chemical potential energy), as some of the chemical potential energy stored in bonds is converted into particle kinetic energy. The increase in particle kinetic energy leads to a rise in the system’s temperature, making it feel hot.

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14
Q

What is chemical potential energy?

A

The energy stored in the chemical bonds of a substance

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15
Q

How is chemical potential energy released?

A

Through a chemical reaction

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16
Q

What is kinetic energy?

A

A form of energy that an object or a particle has by reason of its motion

17
Q

What are endothermic reactions and give an example of one.

A

They are reactions that gain heat from the surroundings (e.g. ice melting)

18
Q

Is the value of enthalpy change negative or positive for an enothermic reaction?

A

Positive because enthalpy increases during the course of the reaction

19
Q

Why do endothermic systems feel cold?

A

Endothermic systems feel cold because energy is absorbed from the surroundings to break bonds. This causes an increase in enthalpy (chemical potential energy) as some of the kinetic energy of the particles is converted into potential energy stored in bonds. The decrease in particle kinetic energy leads to a lower temperature in the reacting system, making it feel cold.

20
Q

What is an energy profile diagram?

A

An energy profile is a representation of a chemical reaction as a single energetic pathway as the reactants are transformed into products.

21
Q

Draw a exothermic energy profile diagram with these labels:
-Products
-Reactants
-Enthalpy change
-Transition state
-Activation energy

A

Answers on page 4

22
Q

Draw a endothermic energy profile diagram with these labels:
-Products
-Reactants
-Enthalpy change
-Transition state
-Activation energy

A

Answers on page 4

23
Q

Is enthalpy change written with the products or reactant for exothermic reactions

A

With the products because heat is being released

24
Q

Is enthalpy change written with the products or reactant for endothermic reactions

A

With the reactants because heat is being absorbed

25
What is a dilute solution?
A dilute solution is a solution in which a small amount of solute is dissolved in a large amount of solvent.
26
What is a concentrated solution?
A concentrated solution is a solution in which the amount of solute dissolved is more compared to the amount of solvent.
27
What is reaction rate?
A measure of the rate at which reactants are consumed or products are formed
28
What increases reaction rate?
-Increased temperature -Increased concentrations -Increased pressure -State of subdivision -Presence of a catalyst
29
What is a catalyst?
Any substance that increases the rate of a reaction without itself being consumed
30
What does collision theory explain?
Why different reactions occur at different rates, and suggests ways to change the rate of a reaction
31
According to collision theory, what conditions must be met for a chemical reaction to occur?
-The reacting particles must collide -The reacting particles must collide with sufficient energy -The reacting particles must collide with the correct orientation
32
What is a transition state?
It is the highest potential energy state for a reaction It is a point in the reaction where new bonds are forming and the original bonds are breaking
33
What is activation energy?
The minimal amount of energy required to form the transition state
34
How does increasing the concentration increase reaction rate?
Increased concentration will increase the reaction rate because there are more reactant particles in a given volume, which according to collision theory, this leads to more frequent collisions, increasing the chances of successful collisions with sufficient energy and correct orientation, which speeds up the reaction. Flashcard version
35
How does increasing the temperature increase reaction rate?
Increasing temperature increases the reaction rate because particles gain more kinetic energy. According to collision theory, this results in more frequent collisions and a greater proportion of particles having energy equal to or greater than the activation energy, increasing the number of successful collisions.
36
How does increasing the gas pressure increase reaction rate?
Increasing the pressure of a gas increases the reaction rate because it compresses gas particles into a smaller volume, increasing their concentration. This leads to more frequent collisions, raising the chance of successful collisions as described by collision theory.
37
How does increasing the state of subdivision increase reaction rate?
In heterogeneous reactions, increasing the surface area of a solid reactant allows more collisions to occur at the surface boundary between phases. Since reactants can only collide at this boundary, a larger surface area leads to more frequent collisions, increasing the rate of reaction according to collision theory.
38
How does a catalyst increase the reaction rate?
A catalyst increases the reaction rate by providing an alternative reaction pathway with a lower activation energy. According to collision theory, this means more collisions occur with enough energy to be successful, increasing the reaction rate without being used up.