Chapter 11 - Basic concepts of organic chemistry Flashcards

1
Q

What is a homologous series?

A

A family of compounds with similar chemical properties whose successive members differ by the addition of a CH2 group

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2
Q

What is a functional group?

A

the part of the organic molecule that is largely responsible for the molecules chemical properties

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3
Q

What are aliphatic hydrocarbons?

A

carbon atoms joined together to each other in unbranched or branched chains

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4
Q

What are alicyclic hydrocarbons?

A

Carbon atoms joined to each other in ring structures

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5
Q

What are aromatic hydrocarbons?

A

Some or all of the carbon atoms are found in a benzene ring

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6
Q

what are the first four alkanes?

A

methane, ethane, propane and butane

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7
Q

What prefix do alicyclic alkanes have?

A

cyclo

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8
Q

What functional group has a c to c double bond?

A

alkene

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9
Q

What functional group has an OH?

A

Alcohol

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10
Q

What functional group has -Cl, -Br and -I ?

A

Haloalkane

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11
Q

What functional group has - CHO?

A

Aldehyde

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12
Q

What functional group has -C(CO)C- ?

A

Ketone

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13
Q

What functional group has -COOH ?

A

Carboxylic acid

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14
Q

What functional group has a -COOC- ?

A

ester

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15
Q

What functional group has -COCl ?

A

acyl chloride

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16
Q

What functional group has a -NH2 ?

A

amine

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17
Q

What functional group has a -CN?

A

nitrile

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18
Q

what is the prefix for alcohols?

A

hydroxy-

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19
Q

What is the prefix for haloalkanes?

A

chloro- bromo- iodo-

20
Q

What is the prefix for amine?

21
Q

what is the suffix for alkenes?

22
Q

what is the suffix for alcohols?

23
Q

what is the suffix for an aldehyde?

24
Q

what is the suffix for a ketone?

25
what is the suffix for carboxylic acids?
-oic acid
26
what is the suffix for an ester?
-oate
27
what is the suffix for an acyl chloride?
-oyl chloride
28
what is the suffix for an amine?
-amine
29
what is the suffix for a nitrile?
-nitrile
30
What is molecular formula?
Shows the number and type of atoms of each element present in a molecule
31
what is empirical formulae?
The simplest whole number ratio of the atoms of each element present in a compound
32
What is general formulae?
simplest algebraic formula for any member of a homogolous series
33
What is a displayed formula?
shows the relative positioning of all of the atoms in a molecule and the bonds between them
34
What is structural formulae?
used the smallest amount of detail necessary to show the arrangement of the atoms in a molecule
35
what is skeletal formulae?
shows the carbon skeleton and any functional groups
36
What are structural isomerisms?
Compounds with the same molecular formula but different structural formulae
37
what are the two ways covalent bonds can be broken?
homolytic fission and heterolytic fission
38
what happens during homolytic fission?
each of the bonded atoms takes one of the shared pair of electrons from the bond
39
what type of atom is a result of homolytic fission?
a radical
40
what happens during heterolytic fission?
one of the bonded atoms takes both of the electrons from the bond
41
what is the result of heterolytic fission?
a negative and a positive ion
42
what do curly arrows show in a reaction mechanism?
the movement of electron pairs when bonds are being broken or made
43
what is addition?
when two reactants join together to form one product
44
what is substitution?
when an atom or group of atoms is replaced by a different atom or group of atoms
45
what is elimination?
involves the removal of a small molecule from a larger one. one reactant molecule forms two products