Chapter 11: Basic Concepts Of Organic Chemistry Flashcards

1
Q

General formula

A

An algebraic formula that can describe any member of a family of compounds.

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2
Q

General formula of an alkane

A

CnH2n+2

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3
Q

General formula of an alkene

A

CnH2n

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4
Q

General formula of an alcohol

A

CnH2n+1OH

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5
Q

General formula of a carboxylic acid

A

CnH2n+1COOH

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6
Q

General formula of a ketone

A

CnH2nO

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7
Q

Empirical formula

A

The simplest whole number ratio of atoms of each element in a compound.

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8
Q

Molecular formula

A

The actual number of atoms of each element in a molecule

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9
Q

Structural formula

A

Shows the arrangement of atoms carbon by carbon, with the attached hydrocarbons and functional groups

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10
Q

Skeletal formula

A

Shows the bonds of the carbon skeleton only, with any functional groups

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11
Q

Displayed formula

A

Shows how all the atoms are arranged, and the bonds between them

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12
Q

Hydrocarbon

A

A compound containing only carbon and hydrogen

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13
Q

Saturated

A

Single bonds only

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14
Q

Unsaturated

A

Carbon-carbon double bonds

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15
Q

Homologous series

A

A family of compounds with similar chemical properties who’s successive members differ by the addition of a -CH2 group.

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16
Q

Aliphatic

A

Carbon atoms are joined to each other in unbranched or branched chains, or non-aromatic rings.

17
Q

Alicyclic

A

Carbon atoms are joined to each other in ring structures, with or without branches.

18
Q

Aromatic

A

Some or all of the carbon atoms are found in a benzene ring

19
Q

Aldehyde suffix

A

-al

20
Q

Ketone suffix

A

-one

21
Q

Carboxylic acid suffix

A

-oic acid

22
Q

Ester suffix

A

-oate

23
Q

Acyl chloride suffix

A

-oyl chloride

24
Q

Amine prefix and suffix

A

Amino-
-amine

25
Q

Nitrile suffix

A

-nitrile

26
Q

Structural isomers

A

Compounds with the same molecular formula but different structural formulae.

27
Q

Chain isomers

A

In chain isomers, the carbon chain is arranged differently. The isomers will have similar chemical properties but different physical properties

28
Q

Positional isomers

A

In positional isomers, the functional group is attached to a different carbon atom. The isomers will have similar chemical properties but different physical properties.

29
Q

Functional group isomers

A

Functional group isomers contain different functional groups and so are members of different homologous series. The isomers will have different chemical properties and different physical properties.

30
Q

Homolytic fission

A

When the covalent bond breaks, each of the bonded atoms takes one of the shared pair of electrons from the bond.

31
Q

Heterolytic fission

A

When a covalent bond breaks by heterolytic fission, one of the bonded atoms takes both of the electrons from the bond.

32
Q

Radical

A

An atom or group of atoms with an unpaired electron

33
Q

Curly arrow

A

The movement of electron pairs when bonds are being broken or made

34
Q

Addition reactions

A

Two reactants join together to form one product

35
Q

Substitution reaction

A

An atom or group of atoms in replaced by a different atom or group of atoms

36
Q

Elimination reaction

A

Involves the removal of a small molecule from a larger one