Chapter 11 Basic Concepts of Organic Chemistry Flashcards
What are hydrocarbons?
Contain carbon and hydrogen atoms only
What are saturated and unsaturated hydrocarbons?
Saturated hydrocarbons have single bonds only
Unsaturated hydrocarbonshave carbon-carbon multiple bonds
What are homologous series?
A family of compounds with similar chemical properties
What are functional groups?
Is the part of the organic molecule that is largely responsible for the molecule’s chemical properties
What are the differences of aliphatic, alicyclic and aromatic?
Aliphatic: carbon atoms are joined to each other in unbranched or branched chain, suffix -ane
Alicyclic: carbon atoms are joined to each other in ring structures, prefix cyclo-
Aromatic: some or all carbon atoms found in a benzene ring, suffix -ene
What is the difference between the different formulas? (molecular, empirical, general, displayed, structural, skeletal)
Molecular: number and type of atoms of each element, doesn’t show how atoms are joined together
Empirical: simplest whole-number ratio of atoms of each element
General: simplest algebraic formula for any member of a homologous series
Displayed: relative positioning of all the atoms in a molecule
Sturctural: which groups are bonded together with the smallest amount of detail
Skeetal: removes carbons and hydrogens
What are isomers?
Different compounds with the same molecular formula
What are structural isomers?
Compounds with the same molecular formula but different structural formulae
Functional groups can be in different positions along the chain
What is homolytic fission?
Each of the bonded atoms take one of the shared pair of electrons, which each atom has a single unpaired electron, forming a radical
What is heterolytic fission?
When one of the bonded atoms takes both of the eletrons from the bond, which forms a positive and negative ion
What are the different reactions?
Addition: two reactants join together to form 1 product
Substitution: an atom or a group of atoms is replaced by a different atom or group of atoms
Elimination: removal of small molecule from a larger one, one reactant forms two products