Chapter 11-Basic concepts of organic chemistry Flashcards

(45 cards)

1
Q

What is organic chemistry?

A

The chemistry of carbon compounds

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2
Q

What is a functional group?

A

A group of atoms that are responsible for the characteristic reaction of a compound

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3
Q

What do functional groups determine?

A

The physical and chemical properties of molecules

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4
Q

What is a homologous series?

A

A group of organic compounds that have the same functional group but each successive member differs by CH₂

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5
Q

What do elements in the same functional group have?

A

Same general formula, similar chemical properties, show gradual changes in physical properties?

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6
Q

What does aliphatic mean?

A

Carbon atoms arranged in straight or branched chains

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7
Q

What does alicyclic mean?

A

Carbon atoms joined in rings that may have branches

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8
Q

What does aromatic mean?

A

A compound containing a benzene ring ⌬

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9
Q

What saturated?

A

A compound only contaning carbon-carbon single bonds

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10
Q

What is unsaturated?

A

A carbon compound containing 1 or more carbon-carbon double or triple bonds

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11
Q

What does a general formula include?

A

The number of carbons and hydrogens in terms of n’s

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12
Q

What does a displayed formula include?

A

All hydrogen and carbons drawn out in a molecule

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13
Q

What does a structural formula show?

A

It is like the molecular formula but shows all the atoms in the compound in order (brackets () go around branches)

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14
Q

What does the skeletal formula include?

A

Points (carbons) joined together by lines (carbon bonds) and functional groups-hydrogens not in functional groups are omitted

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15
Q

What are the first 10 prefixes for carbon chain lengths?

A
  • Meth
  • Eth
  • Prop
  • But
  • Pent
  • Hex
  • Hept
  • Oct
  • Non
  • Dec
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16
Q

What functional group represents a branch off the carbon chain?

A

Alkyl

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17
Q

How are branched hydrocarbons named?

A
  • Find longest carbon chain
  • Name the branches before the carbon chain with their number before hand (separate numbers with commas)
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18
Q

What are the prefixes to use when there are multiple of the same carbon chain coming off the same carbon atom?

A
  • di
  • tri
  • tetra
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19
Q

What is the prefix of cyclic alkanes?

20
Q

What is the prefix for different haloalkanes?

A
  • Fl-Flouro
  • Cl-Chloro
  • Br-Bromo
  • I-Iodo
21
Q

How do you name alkenes?

A
  • Find the longest carbon chain with a double bond
  • The double bond gets the lowest no.
  • The number is between the root and suffix e.g. pent-2-ene
22
Q

What is the functional group and prefix/suffix for Alkenes?

A
  • C=C
  • Suffix-ene
23
Q

What is the functional group and prefix/suffix for Alcohols?

A
  • -OH
  • Prefix-hydroxy
  • Suffix-ol *
24
Q

What is the functional group and prefix/suffix for Haloalkanes?

A
  • C-Halogen
  • Prefix-e.g. chloro
25
What is the functional group and prefix/suffix for Aldehydes?
* C=O (on end of carbon chain) * Suffix-al
26
What is the functional group and prefix/suffix for Ketones?
* C=O (in middle of carbon chain) * Prefix-oxo * Suffix-one*
27
What is the functional group and prefix/suffix for Carboxylic acids?
* -COOH * Suffix-oic acid
28
What is the functional group and prefix/suffix for Nitriles?
* -C≡N * Suffix-nitrile
29
What is the functional group and prefix/suffix for Amines?
* -NH₂ * Prefix-amino * Suffix-amine*
30
What is the naming system called for molecules?
The IUPAC
31
What are structural isomers?
Same molecular formula, different structural formula
32
What are chain isomers?
Different arrangement of carbon skelaton
33
What are the properties of chain isomers?
* Similar chemical properties * Slightly different physical properties
34
What are positional isomers?
Different position of functional group of carbon chain
35
What are properties of positional isomers?
* Similar chemical properties * Slightly different physical properties
36
What are functional group isomers
* Same molecular formula, different functional group
37
What are properties of functional group isomerism?
Different chemical and physical properties
38
What is Heterolytic fission?
The shared pair of electron in a covalent bond goes to one of the atoms in the bond
39
What is Homolytic fission?
Each bond recieves one electron from the covalent bond forming 2 radicals
40
What is a radical?
A species with an unpaired electron
41
How are the movement of single and pairs of electrons shown?
* Single electrons-curly single headed fishhook arrow * Pair of electrons-curly double headed arrow
42
Where can pairs of electrons come from?
* The shared pair of electrons in a covalent bond * A lone pair
43
Where can pairs of electrons go to?
* Another atom, forming a single covalent dative bond between them * Another atom forming a double covalnt bond between them * To a single bond-to become a double bond * To form a lone pair
44
What is a nucleophile?
Electron pair donor
45
What is an electrophile?
Electron pair acceptor