Chapter 12 Flashcards

1
Q
  • gas particles travel in straight lines unless they collide with other particles or the wall of the container
  • Gas particles have negligible volume compared to the free space between them
  • Molecular collisions are perfectly elastic and kinetic energy is conserved
  • there are no attractive or repulsive forces between particles or a gas
  • the average kinetic energy of the particles is proportioned to the absolute temperature
    What does this describe
A

Kinetic molecular theory of matter

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Kinetic theory of liquids describes what

A

*Particles will have less kinetic energy then gaseous state
* Particles have been reduced in kinetic energy and are close enough to form intermolecular forces

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What are 4 properties of water

A

*Definite volume no definite shape
* High density ( 1000x more dense than gas phase)
* Relatively incompressible
* Diffusion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Is water polar or non polar

A

Polar

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

7 Properties of water

A

*Polar
* Excellent solvent
* High heat capacity and heat vaporization
* Has cohesive and adhesive properties
* Capillary action attraction between surfaces of a liquid
* Less dense as a solid then a liquid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What theory consists of small particles that vibrate around fixed positions and have intermolecular forces that are very Strong and the particles are more orderedml.

A

Kinetic theory for solids

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What are the 6 properties of solids

A

*Definite shape and volume
* No - fluid
* High density
* Incompressible
* Slow rate of diffusion
* Definite melting pointn

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What are Crystals definition and traits

A
  • all true solids are made of crystals
  • Composed of repeating orderly basic structures called unit cells
  • Crystal lattice the total 3-d arrangement of the particles of a crystal
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

There are 4 types of crystals what are they

A

*Covalent network
* Metallic Crystals
* Ionic
*Covalent molecular

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What is a covalent network solid ?

A

*The entire network is held together by covalent bonds, not intermolecular forces
* Every hard crystal
* Very high melting point
* Does not dissolve in water
*May conduct electricity in solid state ( graphite )
* entire crystal is the molecule

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Describe a metallic solid

A

*Positive ions surrounded by a sea of electrons ( non directional bond)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What is a non directional bond

A

These bonds are responsible for unique properties of metal
* good conductor
* malleable / ductile
* Shiny
* Ex. Copper, silver, steel

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Ionic solids have 6 traits what are they

A

*Held together by (+)(-) charges
* Soluble in water
* Conduct electricity in the solution or when melted
* High melting points
* Entire crystal is the molecule
* Brittle crystals structure that leaves along a plane
* Ex. NaCl, Ca, F2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Describe the 4 traits of covalent molecular solids

A
  • may dissolve in water
  • Do not conduct electricity in solid or aqueous state
  • have lower melting points
  • can be either polar or non polar depending on the intermolecular forces present
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Describe the two traits of non polar covalent molecular solids

A
  • made up for no polar covalent molecules
  • Held together by only London dispersion forces
  • Ex, I2
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Describe the 4 traits of polar covalent molecular solids

A
  • polar
  • Made up of polar covalent molecules
  • Held together by dipole - dipole attractions
    Or hydrogen bonding ( along with long dispersion forces )
    Ex, H2O, NH3,( ammonia)
17
Q

Amorphous solids have three traits what are they

A
  • have no true crystal structure
  • Have no definite melting point
  • Ex, butter, glass, plastic
18
Q

Dynamic equilibrium has two categoric parts what are they

A

A. Chemical equilibrium
B. Phase Equilibrium

19
Q

What are the 3 points of dynamic equilibrium

A
  • State in which two opposing forces occur simultaneously at equal rates
  • No set change occur
  • called homeostasis for biological organisms
20
Q

What point is under chemical equilibrium

A
  • involves chemical reaction between reactants and products
21
Q

What are the 2 parts of points under phase Equilibrium

A

*Only occurs in a closer container
* Exists between solid, liquid, and gas phase of a substance

22
Q

What is liquid - vapor Equilibrium

A

Rate of evaporation and condensation are equal

23
Q

What is solid - liquid equilibrium

A

Ate of melting and freezing are equal

24
Q

What is solid vapor Equilibrium

A

The rate of sublimation and deposition are equally

25
Temperature + energy = vapor If the temperature is increasing what direction will it go?
Favors forward direction to remove excess energy
26
Temperature liquid + energy = vapor If the temperature is decreasing what direction will it go?
Favors reverse direction ( condensation) to replace the energy that was removed
27
Is evaporation endothermic or exothermic
Endothermic
28
Is condensation endothermic or exothermic
Exothermic
29
Liquid + energy = vapor If the pressure increases what direction will it go
It will go in reverse to remove excess vapor
30
Liquid + energy = Vapor If the Volume increases what direction will it go
It will go forward to replace the vapor
31
Vapor pressure what is it
The presssure exerted by a substance at equilibrium
32
A higher vapor pressure will lead to what?
* weak intermol forces * low boiling point * ex: alcohol, gasoline, perfume
33
A lower vapor pressure leads to what
* strong intermolecular forces * High boiling point * Water, oil
34
Phase change has three categories what are they
Melting point, boiling point, sublimation
35
What is phase change melting point
* the temperature and pressure at which solid becomes a liquid
36
What is phase change boiling point
The temp and pressure at which a liquid and a gas are in equilibrium
37
What is phase change sublimation
*Changing directly from a solid to a Vapor * The temp at which the vapor pressure of the solid phase of a compound is equal to the total pressure of the gas phase with which it is in contact