Chapter 13 in class lecture: Flashcards
(20 cards)
What is the equation for molality?
What is molality used for?
what is the symbol for molality
moles of solute/ kg of solution
- ) volume tends to change with temp, and molality is useful for colligative properties
- ) m
how to solve for mol fraction?
what is the abbreviation of a mol fraction?
when is a mol fraction most commonly used?
- mols of desired component of mixture/ total # of mols in the mixture.
- (x)
- to find partial pressures of gases.
How to solve for mass %?
(mass of desired component/ total mass of solid) * 100%
What is PPM?
What is the equation for PPM?
Parts per million
(mass of desired component/ total mass of solid) x 10 ^6
What is PPB?
What is the equation for PPB?
Parts per billion
(mass of desired component/ total mass of solid) x 10 ^9
What is true of the solubility of solids?
solubility increases as temperature
What is true of the solubility of gases?
solubility of gas in a solution is proportional to the pressure of the gas above the solution
What is Henry’s Law?
solubility of a gas in a solution is equal to: K x P
K= proportionality constant
P= proportionality constant (specific to any given gas)
What are colligative properties?
properties that depend only on the amount of of stuff dissolved in the solution, not on the identity of the stuff.
What are the colligative properties?
- ) vapor pressure lowering/depression
- ) Freezing point depression
- ) Boiling elevation
- ) Osmotic pressure
What equation do you use for vapor pressure lowering?
Raoult’s law: P(solution)= P(solvent) * xXsolvent
Partial Pressure?
{Pressure(substance * mols(substance)} +{Pressure(substance * mols(substance)} + {Pressure(substance * mols(substance)}
What happens to vapor pressure as you add more stuff to the solution?
It lowers
What is the Van’t Hoff factor of a covalent bond if it isn’t stated in the problem?
1
What is the Van’t Hoff factor of a ionic bond if it isn’t stated in the problem?
- the amount of individual atoms or polyatomic ions the substance breaks down into
- Ex: NaCl = I = 2
Describe the process of determining the vapor pressure using the Van’t Hoff Factor:
- 1st you need to get the necessary componets of the problem: mols solute and solvent, Van’t hoff factor, and the pressure of the solute @ T.
- 2nd: mols solute/mols solv + mols solu X I
- 3rd: take this number and multiply it by the P(solu) @ T.
What is the Equation for Bp elevation:
DeltaT(b) = K(b) x m x i Change in boiling point Boiling point elevation molality Van't Hoff Factor
What is the equation for Fp Decline:
DeltaT(f) = -K(f) * m * i
change in freezing point
Freezing point depression constant
What is the equation for Osmosis/Osmotic pressure?
Pi = M * R * T * i (osmotic pressure) Molarity Gas constant Temperature Van't Hoff factor
What does it mean to be spontaneous
requires no energy to complete