Chapter 15 Flashcards

(7 cards)

1
Q

What is hydrolysis

A

Chemical reaction involving water or an aqueous solution of a hydroxide that causes the breaking of a bond in a molecule - splitting into two products

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2
Q

What is the hydrolysis of haloalkane example of?

A

Nucleophilic sub
Halogen replaced by OH group
Alcohol and halide formed
C-X bond breaks by heterolytic fission

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3
Q

Test for rate of hydrolysis of haloalkanes?

A

Add ethanol to each haloalkane and add silver nitrate

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4
Q

Why does the strength of C-X bond decrease down the group

A

Less energy is required to break the bond down the group

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5
Q

Conditions and reagents for conversion from haloalkane to alcohol

A

Sodium hydroxide
Reflux

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6
Q

Why is ethanol used in rate of hydrolysis of haloalkanes?

A

To mix batter and haloalkane as they are insoluble in water

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7
Q

What else takes factor in the rate of hydrolysis

A

Whether it is primary, secondary or tertiary
Primary takes one step mechanism whereas tertiary takes 2 step mechanism

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