Chapter 2 - Atoms and Elements Flashcards

(59 cards)

1
Q

The first people to propose that matter was composed of small, indestructible particles were _________ and his student __________.

A

Leucippus and his student Democritus.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

_________ and __________ proposed that many different kinds of atoms existed, each different in shape and size, and that they moved randomly through empty space.

A

Leucippus and Democritus

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What were the three most important laws that led to the development and acceptance of the atomic theory?

A

The law of conservation of mass, the law of definite proportions, and the law of multiple proportions.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

State the law of conservation of mass.

A

“In a chemical reaction, matter is neither created nor destroyed.”

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

State the law of definite proportions.

A
  • All samples of a given compound have the same proportions of their constituent elements.
  • Compounds have definite proportions of their constituent elements because the atoms that compose them, each with its own specific mass, occur in a definite ratio.
  • Since the ratio of atoms is the same for all samples of a particular compound, the ratio of masses is also the same.
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

In order for the results to be consistent with the law of ________ __________, the ratios must be the same for the two samples.

A

definite proportions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Who published the law of multiple proportions?

A

John Dalton.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

State the law of multiple proportions.

A
  • When two elements (A and B) form two different compounds, the masses of element B that combine with 1g of element A can be expressed as a ratio of small whole numbers.
  • The masses of B that react with a fixed mass of A are always related to one another as small whole-number ratios.
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

State John Dalton’s first postulate on atomic theory.

A
  1. Each element is composed of small, indestructible particles called atoms.
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

State John Dalton’s second postulate on atomic theory.

A
  1. All atoms of a given element have the same mass and other properties that distinguish them from the atoms of other elements.
    - All atoms are unique.
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

State John Dalton’s third postulate on atomic theory.

A
  1. Atoms combine in simple, whole-number ratios to form compounds.
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

State John Dalton’s fourth postulate on atomic theory.

A
  1. Atoms of one element cannot change into atoms of another element.
    - In a chemical reaction, atoms only change the way they are bound together with atoms.
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Who discovered the electron?

A

J.J Thomson.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

What was Robert Millikan’s famous experiment and what did he discover?

A

The oil drop experiment. He discovered the charge of a single electron.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

The mass of an electron is about ____x lighter than hydrogen, the lightest atom.

A

2000x

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

The magnitude of the charge of the electron is of tremendous importance because…

A

it determines how strongly an atom holds its electrons.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

Explain J.J Thomson’s Plum Pudding Model.

A

J.J Thomson proposed that the negatively charged electrons were small particles held within a positively charged sphere.
-Think of a blueberry muffin; the blueberries being the electrons and the rest of the muffin being the positively charged sphere.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

__________ - the emission of small energetic particles from the core of certain unstable atoms.

A

Radioactivity

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

What are the three different types of radioactivity?

A

Alpha particles, beta particles, and gamma rays.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

Ernest Rutherford, who had worked under ________ and subscribed to his plum pudding model, performed an experiment in order to confirm ________’s model.

A

Thompson

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

Ernest Rutherford is famous for his ____ _____ experiment

A

gold foil

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

Rutherford’s experiment, which employed _____ particles, proved it wrong instead.

A

alpha

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
23
Q

In Rutherford’s experiment, if the gold atoms were indeed like blueberry muffins or plum pudding - with their mass and charge spread throughout the entire volume of the atom, these speeding probes would pass right through the gold foil with _______ deflection

A

minimum

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
24
Q

Rutherford concluded that, in contrast to the plum-pudding model, matter must not be as uniform as it appears. It must contain large regions of empty space dotted with small regions of very dense _____.

25
Rutherford proposed the ______ theory of the atom, with three basic parts.
nuclear
26
What are the three parts to Rutherford's nuclear theory of the atom?
1. Most of the atom's mass and all of its positive charge are contained in a small core called the nucleus. 2. Most of the volume of the atom is empty space, throughout which tiny, negatively charged electrons are dispersed. 3. There are as many negatively charged electrons outside the nucleus as there are protons within the nucleus, so the atom is electrically neutral.
27
Is Rutherford's theory still valid today?
Yes.
28
Protons and neutrons have almost identical _____.
masses
29
The most important number to identity of an atom is the number of _______ in its nucleus.
protons
30
The number of protons in an atom's nucleus is its ______ ______, and is given the symbol _.
atomic number, Z
31
Since neutrons nearly have the same mass as protons, this mean that - contrary to what John Dalton originally proposed in his atomic theory - all atoms of a given element DO NOT have the same mass. Which of Dalton's four postulates on atomic theory does this prove false?
The second, stating that all atoms of a given element have the same mass and other properties that distinguish them from the atoms of other elements.
32
Atoms with the same number of protons but different number of neutrons are called ________.
Isotopes.
33
The sum of the number of neutrons and protons in an atom is its ____ _______ and is represented by the symbol _.
mass number, A
34
During chemical changes, atoms can lose or gain electrons and become charged particles called ____.
ions
35
Positively charged ions are called _______, while negatively charged ions are called ______.
cations, anions
36
Mendeleev found that when he listed elements in order of increasing mass, these similar properties recurred in a periodic pattern. He summarized these observations in the _______ law.
periodic
37
What does the periodic law state?
When the elements are arranged in order of increasing mass, certain sets of properties recur periodically.
38
In the modern periodic table, elements are listed in order of increasing ______ ______ rather than increasing relative mass.
atomic number
39
What are properties of metals?
- good conductors of heat and electricity - can be pounded into flat sheets (malleability) - can be drawn into wires (ductility) - often shiny - tend to lose electrons when they undergo chemical changes
40
What are the properties of nonmetals?
Nonmetals have varied properties. Some are solids at room temperature, others are liquids or gases, but as a whole, they tend to be: - poor conductors of heat and electricity - tend to gain electrons when they undergo chemical changes
41
Many of the elements that lie along the zigzag diagonal line divides metals and nonmetals are _________ and exhibit mixed properties.
metalloids
42
Several metalloids are also classified as __________ because of their intermediate (and highly temperature dependent) electrical conductivity
semiconductors
43
The group 1A elements, called the ______ ______, are all reactive metals.
alkali metals
44
The group 2A elements, called the ________ _____ _____, are also fairly reactive, although not quite as reactive as the alkali metals.
alkaline earth metals
45
The group 7A elements, the _______, are very reactive nonmetals.
halogens
46
In chemical reactions, metals tend to ____ electrons (forming ______) and nonmetals tend to _____ them (forming ______)
Metals tend to lose electrons, forming cations. | Nonmetals tend to gain electrons, forming anions.
47
Main group elements tend to form ions that have the same number of electrons as the nearest _____ ___.
noble gas
48
* **A main-group metal tends to ____ electrons, forming a cation with the same number of electrons as the nearest noble gas. * **A main-group nonmetal tends to ____ electrons, forming an anion with the same number of electrons as the nearest noble gas.
lose, gain
49
The atomic mass represents the average mass of the _______ that compose that element, weighted according to the natural abundance of each isotope.
isotopes
50
Atomic mass is a _______ average.
weighted
51
How do you calculate atomic mass?
a.m = ab1 * mass of isotope 1 + ab2 * mass of isotope 2, etc.
52
The masses of atoms and the percent abundances of isotopes of elements are measured using ____ _________, a technique that separates particles according to their mass.
mass spectrometry
53
1 mole =
6.022x10^23 particles
54
The value of the mole is equal to the number of atoms in exactly 12 grams of pure ______ -12 (12g _ = 1 mol _ atoms = 6.022x10^23 _ atoms)
Carbon, C
55
An element's molar mass in grams per mole is numerically _____ to the element's atomic mass in atomic mass units.
equal
56
For the isotope carbon-12, we know that the mass of 1 mol of atoms is exactly __ grams, which is numerically equivalent to carbon-12's atomic mass in atomic mass units.
12
57
For example, copper has an atomic mass of 63.55 amu and a molar mass of __.__ g/mol. One mole of copper atoms therefore has a mass of 63.55g.
63.55
58
12.01 g C =
1 mol C
59
What idea came out of Rutherford's gold foil experiment?
Atoms are mostly empty space.