Chapter 20/21 Flashcards
(14 cards)
How to find pH when [H+] is known?
pH = -log[H+]
How to find [H+] when given pH?
[H+] = 10^-pH
How to find Kw in aqueous solutions?
Kw = [H+] x [OH-]
How to find Ka when a weak acid is in an aqueous solution?
Ka = ([H+] x [A-]) / [HA]
How to get pKa from Ka?
pKa = -logKa
What is [HA]?
Concentration of acid
What is [H+]?
Concentration of Hydrogen ions
What is [A-]?
Concentration of conjugate base
How to get pH of a strong acid?
pH = -log[HA]
This is because [HA] = [H+] as it can fully dissociate
What is a Brønsted-Lowry acid?
A species that dissociates in aqueous solutions to produce H+ ions
What is a Brønsted-Lowry alkali?
A species that dissociates in an aqueous solution to produce OH- ions
What is a buffer?
A solution that can minimise changes to pH when small amounts of acid or base are added
What happens when acid is added to a buffer?
- H+ conc increases
- H+ reacts with A-, forming more HA
- Equilibrium shifts to the left
What happens when alkali is added to a buffer?
- OH- conc increases
- H+ reacts with OH- to form water
- HA dissociates to replace used H+, shifting equilibrium to the right