Chapter 21 - Nuclear Chemistry Flashcards

(36 cards)

0
Q

Atomic number

A

Number of protons

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1
Q

Nucleons

A

Protons, neutrons, electrons

Nucleus is composed of the first two

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2
Q

Mass of atom

A

Number of protons and neutrons

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3
Q

Isotopes happen because

A

Varying neutrons

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4
Q

Radioactive

A

Unstable

Not uncommon for nuclides aka radionuclides

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5
Q

Alpha decay

A

Loss of an alpha particle (a helium nucleus)

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6
Q

Beta decay

A

Loss of the beta particle (a high energy electron)

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7
Q

Positron emission

A

Nuclei decay by emitting a positron a particle hay has the same mass as but and opposites charge to that of an electron
0
e
1

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8
Q

Gamma emission

A

The loss of a gamma ray which is high energy radiation that almost always accompanies the loss of a nuclear particle
0
0

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9
Q

Electron capture

A

Addition of an electron to a proton in the nucleus

Result is a neutron

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10
Q

Neutron-proton ratios

A

Any element with more than one proton will have repulsions between the protons in the nucleus

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11
Q

What helps keep the nucleus from flying apart?

A

A strong nuclear force

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12
Q

Neutrons key role

A

Stabilizing the nucleus

The ratio of neutrons to protons is an important factor

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13
Q

For smaller nuclei the neutron - proton ratio

A

Is close to 1:1 when z< 21

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14
Q

As nuclei get larger the number of neutrons needed to stabilize the nucleus

A

Increases

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15
Q

Belt of stability

A

Blue dark dots that show what nuclides would be stable

16
Q

Above the belt of stability

A

Above the belt have too many neutrons (tend to be emitting beta particles)

17
Q

Below the belt of stability

A

Nuclei have too many protons

Can become more stable by positron emission or electron capture

18
Q

There are no stable nuclei with an atomic number greater than

A

83

These nuclei tend to decay by alpha emission

19
Q

Large radioactive nuclei and stabilization

A

Cannot stabilize from one nuclear transformation

Undergo a series of decays often forming a nuclide of lead

20
Q

Trends of number of protons and neutrons dealing with stability

A

Even is more stable than odds

21
Q

How can one tap all the energy of a nucleus

A

Nuclear fission

Starts with the bombardment with a neutron which causes the decay and production of more neutrons (nuclear chain reaction)

22
Q

Critical mass

A

Rate of neutron loss = rate of neutron creation by fission

23
Q

Manhattan project

A

Development of the a bomb in WWII

Lead by Oppenheimer and groves

Used uranium 235

24
Curie/becquerel
Amt of radiation emitted by material
25
Rad/gray
Radiation dose absorbed by a person
26
Rem/sievert
Biological risk of exposure to radiation
27
Geiger counter
Used to measure the amount of activity present in radioactive sample Detects current of ions
28
Kinetics of radioactive decay
Nuclear transmutation is a first order process Kinetics of such a process obey this eqn: ln(Nt/N0) = -kt
29
Half life of radioactive decay
0.693/k
30
Radiocarbon dating
By comparing amount of a radioactive nuclide present at a given point in time with the amount normally present we can find the age of an object
31
Nuclear reactors
In nuclear reactors the heat generated by the reaction is used to produce steak that turns a turbine connected to a generator Reaction is kept in check by control rods by blocking the paths of some neutrons
32
Nuclear accidents
Three mile island Chernobyl Fukushima
33
How can nuclear transformations be induced
By acceleration a particle and colliding it with the nuclide
34
Particle accelerator
Enormous Circular tracks Radii is miles long
35
Nuclear fusion
Superior method of generating power Products not reactive To achieve fusion the material must be state of plasma (super hot)