chapter 3 and 4 Flashcards

(58 cards)

1
Q

Phase

A

Matter which is homogeneous throughout in both its chemical and physical structure. ex- air = single phase
water with ice = 2 phase

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2
Q

Homogeneous

A

Matter is all the same state, solid, liquid, or gas

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3
Q

Pure Substance

A

A substance that is uniform and invariable in chemical composition. ex- helium, water and ice

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4
Q

liquid to gas

A

Vaporization

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5
Q

gas to liquid

A

Condensation

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6
Q

solid to liquid

A

Melting (fusion)

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7
Q

liquid to solid

A

freezing

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8
Q

solid to gas

A

sublimation

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9
Q

gas to solid

A

deposition

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10
Q

Phase Rule

A
f=c-p+2
f= degrees of freedom
c=number of components
p=number of phases
 at equilibrium for a system of any composition.
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11
Q

The ______ state of a closed system at equilibrium is its condition as described by the values of its intensive thermodynamic properties.

A

intensive

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12
Q

For a simple compressible system, specifying any _____ independent intensive thermodynamic properties will fix the other intensive thermodynamics properties of the system.

A

2

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13
Q

Examples of intensive properties

A

(Doesn’t depend on amount of matter or size)

Pressure, Temperature, Density, Specific Volume, Internal Energy, Enthalpy, Entropy.

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14
Q

saturation temperature

A

temp at which a phase change happens for a specific pressure

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15
Q

True or false. Within two-phase regions, pressure and temperature ARE independent.

A

False

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16
Q

Critical point

A

the point where saturated liquid and saturated vapor lines meet

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17
Q

isotherms

A

line of constant temperature

High left to low right on p-v

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18
Q

isobar

A

line of constant pressure

low left to high right t-v

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19
Q

true of false. while in dome if p-v or t-v diagram temp and pressure remain constant from specific volume changes

A

true

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20
Q

compressed liquid

A

a liquid with a temp lower than saturation temp for

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21
Q

quality (x) equation

A

percent of mixture that is vapor

x=mvapor/(mliquid+mvapor)

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22
Q

superheated vapor

A

when temp is higher than the sat temp for corresponding pressure

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23
Q

total volume saturated liquid formula

A

V=vf+x(vg-vf)

vf=liquid vg=vapor

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24
Q

specific enthalpy (h)

A

h=u+pv

enthalpy= internal energy + work due to expansion

25
linear interpolation
vactual= v@ref1 +[(v@ref2 - v@ref1)/(ref2-ref1)] (actual-ref1)
26
Extensive form of internal energy and enthalpy
U and H (uppercase is important)
27
Intensive form of internal energy and enthalpy
u and h (lowercase is important)
28
Constant volume process equation
u2-u1=cv(T2-T1)
29
Constant pressure process equation
h2-h1=cp(T2-T1)
30
specific heat ratio
k=cp/cv
31
True of False. For a liquid, there is little change in v,u,h,and s at different Temperatures and fixed Pressure.
False | there is little change at different Pressures and fixed temperature.
32
incompressible substance
any substance whose properties do not change with pressure, or have very minor changes.
33
generalized compressibility only applies to _____
gases
34
what does a horizontal line above a variable mean
molar unit. | unit times molar weight (g/mol)
35
what does it mean when z=1
ideal gas P is much less than Pc T is much greater than Tc
36
pressure and temp reduced equations
Pr=P/Pc Pc=critical pressure | Tr=T/Tc Tc=critical temp
37
ideal gas equation (3 forms)
pv=RT (lowercase v is important) pV=mRT m=mass pV=nRT (with line above R) n=number of moles
38
if a gas behaves as an ideal gas, then its specific internal energy and specific enthalpy, depends only on _____
temperature
39
polytropic process formula and process for N=1,0,and k
pv^N=constant or pV^N=constant N=1 - isothermal pv=Constant N=0 isobaric process p=Constant N=k adiabatic process Q=0
40
Mass rate balance
the rate at which mass accumulates in the control volume is the difference between mass flow in and flow out
41
Energy rate balance
the rate at which energy accumulates. the difference between heat flow rate in and power out AND difference between mass carries energy into and out of control volume
42
1st law of thermodynamics for open system
rate of energy accumulation= Qdot - Wdot +mdot-i (ei) - mdot-e (ee)
43
Flow work
work done BY the flow (Wdot)
44
control volume work
work done BY the control volume (Wdot-cv) integral of pdv | ex - work done by turning a shaft or electricity
45
work done ON system by mass entering
negative
46
work done On environment as mass exits
positive
47
steady state Qdot=0 if | *IMPORTANT*
small surface area system is insulated small time interacting with system and environment
48
steady state Wdot=0 if | *IMPORTANT*
no change in system volume (fixed container) | no turbines/pumps or electrical devices
49
steady state gz=0 if | *IMPORTANT*
no significant change in elevation from inlet and outlet
50
vi^2-ve^2=0 if | *IMPORTANT*
inlet and outlet are the same size
51
Nozzle
passage where velocity increases in direction of flow Ve greater than Vi Pe less than Pi Enters wide end exits narrow end
52
diffuser
passage where velocity decreases in direction of flow Ve less than Vi Pe greater than Pi enters narrow end, exits wide end
53
Turbine
a device in which --power is developed-- as a result of a gas or liquid passing through a set of blades attached to a shaft free to rotate.
54
compressors and pumps
devices in which --work is done on the substance-- flowing through them to change the state of the substance, typically to --increase the pressure and/or elevation--
55
difference between compressor and pump
compressor- uses gas | pump - uses liquid
56
Heat exchanger | Direct contact
a mixing chamber in which hot and cold streams are --mixed directly-- ex- water faucet
57
heat exchanger | tube-within-a-tube counterflow
a gas or liquid steam is --separated-- from another gas or liquid by a wall through which energy is conducted. heat transfer occurs from the hot stream to the cold stream as the streams flow in opposite directions. ex- radiator
58
specific heat (c) definition
The heat required to raise the temperature of a unit mass of a substance by a certain amount. (usually 1 degree)