chapter 3 p1 Flashcards
Molecules are built from
atoms.
atoms are built from
smaller components including protons, neutrons, and electrons
Elements:
Different types of atoms
are distinguished by the number of protons in their atomic nuclei.
There are over a hundred known elements in the universe but only a small percentage of these are present in the living world.
all living things are made primarily from four key elements:
carbon (C), hydrogen (H), oxygen (0) and nitrogen (N).
In addition, phosphorus (P) and sulfur (S) also have important roles in the biochemistry of cells.
These six elements are the most abundant elements present in biological molecules.
Other elements, including sodium (Na), potassium (K), calcium (Ca), and iron (Fe), also have important roles in biochemistry.
Bonding:
Atoms connect with each other by forming bonds.
Atoms can bond to other atoms of the same element, or atoms of different elements, provided this follows the ‘bonding rules’
When two or more atoms bond together the complex is called a molecule.
A covalent bond occurs when two atoms share a pair of electrons.
The electrons used to form bonds are unpaired and present in the outer orbitals of the atoms.
Life on this planet is often referred to as being ‘carbon-based’ because carbon, which can form four bonds, forms the backbone of most biological molecules.
Bonding follows some simple rules, determined by the number of unpaired electrons present in the outer orbitals of different elements:
Carbon atoms can form four bonds with other atoms.
Nitrogen atoms can form three bonds with other atoms.
Oxygen atoms can form two bonds with other atoms.
Hydrogen atoms can only form one bond with another atom.
Ions:
An atom or molecule in which the total number of electrons is not equal to the total number of protons
cation.
If an atom or molecule loses one or more electrons it has a net positive charge
anion
If an atom or molecule gains electrons, it has a net negative charge
In ionic bonds
one atom in the pair donates an electron and the other receives it.
This forms positive and negative ions that are held together by the attraction of the opposite charges.
electrolytes:
Ions in solution are called
following tables list some of the important roles of ions in living organisms: cations
following tables list some of the important roles of ions in living organisms: anions
Carbohydrates elements
carbon, hydrogen, and oxygen, usually in the ratio Cx(H20)x
Lipids elements
carbon, hydrogen, and oxygen.
Proteins elements
carbon, hydrogen, oxygen, nitrogen, and sulfur.
Nucleic acids
carbon, hydrogen, oxygen, nitrogen, and phosphorus.
Polymers:
Biological molecules are often polymers.
Polymers are long-chain molecules made up by the linking of multiple individual molecules (called monomers) in a repeating pattern.
In carbohydrates the monomers are sugars (saccharides) and in proteins the monomers are amino acids.
Water
The bonds of life:
p1
- Atoms join together to form molecules by making bonds with each other.
- In ionic bonds, atoms give or receive electrons.
- They form negative or positive ions that are held together by the attraction of the opposite charges.
- Covalent bonds occur when atoms share electrons.
- However, the negative electrons are not always shared equally by the atoms of different elements.
- In many covalent bonds, the electrons will spend more time closer to one of the atoms than to the other.
- The atom with the greater share of negative electrons will be slightly negative compared with the other atom in the bond, which will therefore be slightly positive (Figure 1).
Water
The bonds of life:
p2
- Molecules in which this happens are said to be polar - they have regions of negativity and regions of positivity.
- Oxygen and hydrogen are examples of elements that do not share electrons equally in a covalent bond.
- Oxygen always has a much greater share of the electrons in an 0—H bond.
- Many organic molecules contain oxygen and hydrogen bonded together in what are called hydroxyl (OH) groups and so they are slightly polar.
- Water (H2O) is an example of such a molecule, in fact, water contains two of these hydroxyl groups (Figure 2).
formation of hydrogen bonds
- Polar molecules, including water, interact with each other as the positive and negative regions of the molecule attract each other and form bonds, called hydrogen bonds.
- Hydrogen bonds are relatively weak interactions, which break and reform between the constantly moving water molecules.
- Although hydrogen bonds are only weak interactions, they occur in high numbers.
- Hydrogen bonding gives water its unique characteristics, which are essential for life on this planet.