Chapter 4 : Chemical bonds Flashcards
(22 cards)
What is an ion ?
Action(+) >Monatomic *Na+ Fe3+ Derive from 1 atom >polyatomic *Derive from two or more atoms connected with covalent bond NH4/+ H3O+
Cations(-)
>Monatomic Cl- O2-
>Polyatomic NO3/- PO4/3-
How the elemets are closes?
Elements close to the noble gases in the periodic table tend to gain a loose e- is in order to acheve to gain stable noble gase configuration.
General properties of metals and non metals
Metals are silvery shiny solids at room temperature except one: Mercury. Metals can be mated when a metal are good conductors of heat and electrisit
Metal have low ionization energies and low e- affinities. They will form positive cations. Might be solid, liquid, gas. You cannot pound of them because they break. They do not conduct heat and electrisity well. They have high inization and electron energy.
What is the name for 8e-?
called octelulmetal loose electrons, but do not become nobel gases because of neutron same as proportion.
Isoelectromic
These anion are called noble gas type of ion.
Type of ions
> Ion can be two types 2+ or 3+
Electrons are always removed from the orbital
Most table:noble element
2nd most stbale is when subshell has all his orbitals helpfull with orbitals =half filled subshells
Electrostatic attraction
its a large number of cation, anions and anions ions arranged in a definit pattern called “crystal lattice”. Formule express only the simplest proportion of the ions in the compounds.
Emirical formula
shows the simplest proportion of he atoms in the compounds.
Ionic compounds
the formula is always the same as the empirical formula
the sum of the charges on the cation and anios in each formula unit must equal zero.
Covalent bond
is a chemical bond in wich two or more e- are shared by 2 atoms.
Electrons: alone or with something?
e- are always in pairs either in bonding pairs or membording pair .
e- alone is calld “free radical”
Cordinate covalent bonds
A coordinate covalente bond is a bnd formed when one atom donates both electrons that are shared.
Bond polarity
A polar covalent bond is a covalent bond ith greater e- density around one of the 2 atoms
electronegativity
is the ability of an atom to attarct toward itself the electrons in a chemical bond.
Polar or apolar?
Apolar, non polar is symetrical
Polar is asymetrical e- distribution electrical dipoles.
Molecular Geometry VSEPR model
consider 2 things
> the polary of the covalent bond (difference in e- negativity)
>The shape of the molecule (3D shape)
What is a shape for a molecule?
The shape of a molecule is determining by the number of electrons parts that surronds the central atoms.
2e-p?
Cl-Be-Cl linear molecule very polar (exception)
Electronegativity difference be have as vectors, they many cancel each other.
3e-p?
around the central atom=trianglar
Due to the symetrical shape its not polar as they cancel.
4e-p?
tetrahedral shape
this whole molecule is non polar because they cancel due to the symetrie.
Double and triple bond
occupy space only one direction. When we want to determine the hape with the usepr model, e- and multiple bonds cant as if they were single bonds
Delocalisation e-
means e- to not be long strickly to 2 atoms but spreads as a cloud ever larger area.