Chapter 4 - Chemical Foundations: Elements, Atoms, and Ions Flashcards

(42 cards)

1
Q

What are the 2 applications of chemistry that were used before 1000 BC?

A

the processing of ores to produce metals for ornaments and tools and the use of embalming fluids

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2
Q

What were the four fundamental substances that the Greeks had proposed matter to have composed of in 400 BC?

A

fire, earth, water, and air

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3
Q

Some alchemists were what?

A

mystics and fakes who were obsessed with the idea of turning cheap metals into gold

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4
Q

Which elements were found by alchemists?

A

mercury, sulfur, and antimony

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5
Q

What did alchemists learn how to do?

A

to prepare acids

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6
Q

Who was the first scientist to recognize the importance of careful measurements?

A

Robert Boyle (1627-1691)

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7
Q

What was Boyle’s most important contribution to science?

A

his insistence that science should be firmly grounded in experiments (his definition of element was based on experiments)

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8
Q

Why couldn’t air be considered an element?

A

because it could be broken down into many pure substances

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9
Q

All matter can be broken down chemically into about how many different elements?

A

100

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10
Q

How many different elements are known? And how many of those occur naturally?

A

115; 88

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11
Q

What are the 5 most abundant elements in the Earth’s crust, oceans and atmosphere? (List in order of abundance)

A

Oxygen (49.2%), silicon (25.7%), aluminum (7.50%), iron (4.71%), calcium (3.39%)

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12
Q

What are the elements that are the basis for all biologically important molecules?

A

Oxygen, carbon, hydrogen, and nitrogen

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13
Q

What are trace elements?

A

elements found in the body that are crucial despite their small amounts

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14
Q

how many known substances are composed of elements?

A

millions

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15
Q

What is the microscopic form of an element?

A

the single atom of the element

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16
Q

What is the macroscopic form of an element?

A

a sample of the element large enough to weigh on a balance

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17
Q

What does the law of constant composition state?

A

a given compound always has the same composition regardless of where it comes from

18
Q

State Dalton’s atomic theory (1808)

A

1) elements are made of tiny particles called atoms
2) all atoms of a given element are identical
3) the atoms of a given element are different from those of any other element
4) atoms of one element can combine with atoms of other elements to form compounds. A given compound always has the same relative numbers and types of atoms
5) atoms are indivisible in chemical processes. Atoms are not created or destroyed in chemical reactions. A chemical reaction simply changes the way the atoms are grouped together

19
Q

Who was J.J. Thomson?

A

showed that all types of atoms must contain negative particles or electrons; he also concluded that atoms contained positively charged particles to balance the electrons

20
Q

Who was William Thomson or Lord Kelvin?

A

introduced the plum-pudding model of an atom

21
Q

Who was Ernest Rutherford?

A

introduced the idea of a nuclear atom, contrary to the plum pudding model

22
Q

What is a nuclear atom?

A

atom with a dense center of positive charge (nucleus) surrounded by tiny electrons moving in empty space

23
Q

When did Rutherford conclude that the nucleus of the atom contained protons?

24
Q

Who showed that nuclei contained neutrons?

A

Rutherford and James Chadwick (1932)

25
What is the diameter of the nucleus of an atom?
10^ -13 cm
26
What is the average distance of electrons from the nucleus?
10^ -8 cm
27
The proton's positive charge is equal to what?
the negative charge of the electrons
28
Why do different atoms have different chemical properties?
the number and arrangement of electrons
29
What accounts for most of the atomic volume?
The space in which the electrons move
30
Which subatomic particle is in charge of intermingling when atoms combine to form molecules?
electrons
31
The number of what greatly affects the way elements can interact with other atoms?
electrons
32
What determines the atom's chemical behavior?
the number of electrons
33
The number of protons is always equal to the number of electrons. True or false?
true
34
What are isotopes?
atoms with the same number of protons but different number of neutrons
35
what is the atomic number?
The number of protons
36
What is the mass number?
the sum of the number of neutrons and protons
37
A free atom has what charge?
a net zero charge
38
What is chemistry?
The study of matter and how it reacts
39
What is a chemical?
A substance with known composition
40
What is the average atomic mass?
The average of all the mass of the given element
41
1 mole=
6.022*10^23 (atoms, molecules, units)
42
1 mole=what part of the periodic table?
The average atomic mass (g)