Chapter 4: Periodicity Flashcards

(73 cards)

1
Q

How are elements arranged in the Periodic Table?

A

By increasing atomic number.

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2
Q

What do the vertical columns in the Periodic Table represent?

A

Groups.

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3
Q

What do the rows in the Periodic Table represent?

A

Periods.

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4
Q

What trend is observed in atomic radii across a period?

A

Atomic radii decrease.

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5
Q

Why do atomic radii decrease across a period?

A

Increased nuclear charge pulls electrons closer.

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6
Q

What trend is observed in atomic radii down a group?

A

Atomic radii increase.

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7
Q

Why do atomic radii increase down a group?

A

More electron shells increase shielding.

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8
Q

How does the size of positive ions compare to their parent atoms?

A

Positive ions are smaller.

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9
Q

How does the size of negative ions compare to their parent atoms?

A

Negative ions are larger.

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10
Q

What is the trend in ionic radii for positive ions from Groups 1 to 14?

A

Ionic radii decrease.

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11
Q

What is the trend in ionic radii for negative ions from Groups 14 to 17?

A

Ionic radii decrease.

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12
Q

Why do ionic radii decrease across a period?

A

Increased nuclear charge.

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13
Q

What is the trend in ionic radii down a group?

A

Ionic radii increase.

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14
Q

What is the general trend of ionization energy across a period?

A

Ionization energy increases.

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15
Q

Why does ionization energy increase across a period?

A

Greater nuclear attraction makes electrons harder to remove.

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16
Q

What is the general trend of ionization energy down a group?

A

Ionization energy decreases.

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17
Q

Why does ionization energy decrease down a group?

A

Increased distance reduces nuclear attraction.

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18
Q

What is electronegativity?

A

An atom’s ability to attract electrons in a covalent bond.

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19
Q

What is the trend in electronegativity across a period?

A

Electronegativity increases.

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20
Q

What is the trend in electronegativity down a group?

A

Electronegativity decreases.

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21
Q

Which element has the highest electronegativity?

A

Fluorine (4.0).

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22
Q

Which element has the lowest electronegativity?

A

Caesium (0.7).

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23
Q

What happens to melting points down Group 1?

A

Melting points decrease.

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24
Q

Why do melting points decrease down Group 1?

A

Decreased attraction between delocalized electrons and ions.

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25
What happens to melting points down Group 17?
Melting points increase.
26
Why do melting points increase down Group 17?
Stronger London dispersion forces.
27
What is the general trend in melting points across a period?
Increase to Group 14
28
How does bonding change in Period 3?
Metallic → Giant covalent → Van der Waals forces.
29
What ions do Group 1 elements form?
Single positive ions (M+).
30
How do alkali metals react with water?
Form hydrogen and metal hydroxide.
31
What ions do Group 17 elements form?
Single negative ions (M-).
32
How do halogens react with Group 1 metals?
Form ionic halides.
33
Why does chlorine displace bromide in reactions?
Chlorine has a stronger attraction for electrons.
34
What type of molecules do halogens exist as?
Diatomic molecules (X2).
35
What is the bonding nature of metallic oxides in Period 3?
Ionic and basic.
36
What is the bonding nature of non-metallic oxides in Period 3?
Covalent and acidic.
37
What are amphoteric oxides?
Oxides reacting with both acids and bases.
38
Which Period 3 oxide shows amphoteric behavior?
Aluminium oxide.
39
What holds Group 1 elements together in metallic structures?
Delocalized electrons and positive ions.
40
What causes London dispersion forces to increase?
More electrons in a molecule.
41
What trend occurs in metallic character across a period?
Decreases.
42
What trend occurs in non-metallic character across a period?
Increases.
43
Why do metallic structures have high melting points?
Strong metallic bonds.
44
What determines bond type in covalent bonds?
Electronegativity difference.
45
What type of bond forms if electronegativity difference is high?
Ionic bond.
46
What type of bond forms if electronegativity difference is low?
Covalent bond.
47
What group contains the most reactive metals?
Group 1.
48
What group contains the most reactive non-metals?
Group 17.
49
What happens to reactivity in Group 1 down the group?
Increases.
50
What happens to reactivity in Group 17 down the group?
Decreases.
51
What causes reactivity to increase in Group 1?
Easier electron loss.
52
What causes reactivity to decrease in Group 17?
Harder electron gain.
53
How does Group 1 store energy in reactions?
As exothermic heat.
54
What happens to density down Group 1?
Density increases.
55
What color are halogens in their elemental state?
Varies (e.g.
56
What holds diatomic halogen molecules together?
Covalent bonds.
57
What trend occurs in atomic mass across a period?
Atomic mass increases.
58
How does electron shielding change down a group?
Increases.
59
Why is shielding constant across a period?
Same principal quantum shell.
60
What group does helium belong to?
Group 18 (Noble gases).
61
What is a characteristic of noble gases?
Inert and unreactive.
62
What phase are most Group 17 elements at room temperature?
Gases or liquids.
63
What is the most abundant alkali metal?
Sodium (Na).
64
What causes boiling points to increase in halogens?
Stronger intermolecular forces.
65
What type of lattice does NaCl form?
Ionic lattice.
66
Why does silicon have a high melting point?
Giant covalent structure.
67
Why does argon have a low boiling point?
Weak van der Waals forces.
68
What is the electron configuration of a sodium ion (Na+)?
1s² 2s² 2p⁶.
69
What determines the strength of London dispersion forces?
Number of electrons.
70
What defines Group 18 elements?
Full valence shell.
71
How are period trends observed in electronegativity?
Left to right increase.
72
What reaction product forms when halogens gain an electron?
Negative ions (X-).
73
Why are alkali metals stored under oil?
To prevent reaction with air or water.