Chapter 5 Flashcards

(23 cards)

1
Q

Properties of gas

A

-no shape or volume
-fits any container uniformly
-exerts pressure on surroundings
-change V with Temp and pressure
-miscible-mixes together in any proportion
-less sense than solids or liquids

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2
Q

Pressure formula

A

P=Force
———-
Area

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3
Q

Atmospheric pressure

A

Force exerted by gases surrounding earth on earths surface

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4
Q

Units of pressure

A

SI units= Newton/meter^2=1 pascal(Pa)
1atm=101 325 Pa
1atm=760mmHg=760torr

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5
Q

Barometer

A

Measures atmospheric pressure

Height of Hg column
(Gravity pulls Hg down/ atmospheric pressure pushes it up)

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6
Q

Boyles law

A

PV=constant

P=constant(1/V)

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7
Q

Charles law

A

V/T=constant

V1/T1=V2/T2

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8
Q

Avragadros law

A

Volume is directly proportional to number of moles of gas

V/n=constant

V1/n1=V2/n2

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9
Q

Amontons law

A

P/T= constant

P1/T1=P2/T2

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10
Q

Ideal gas law

A

PV=nRT

P-pressure (atm)
V-Volume (L)
n-moles
R-universal gas constant (0.08206 L•atm/K•mol

Allows calculation of gas properties when more than 1 variable is changing

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11
Q

Combined gas law

A

Combines Boyles/Charles/Avagadros/

PV/nT=constant(R)

If n is constant then

P1V1/T1=P2V2/T2

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12
Q

STP

A

Standard temp and pressure

P= 1 atm

T=273K (0.0°C)

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13
Q

Molar volume

A

V=22.4L

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14
Q

Density in gases

A

D=m/V= (pressure)(molar mass)/(ideal gas constant)(Temp)

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15
Q

Ideal gas constant

A

0.0821 L•atm/mol•K

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16
Q

Dalton’s law of partial pressure

A

Pressure depends on the total moles not the identity of the gas

17
Q

A

Means proportional to

1 side is constant of the other

18
Q

Mole fraction

A

Ratio of number of moles of a component in a mixture to the total number of moles in a mixture

Xx=nx/ntotal=nx/n1+n2+n3…

19
Q

Mole fraction in terms of pressure

20
Q

Partial pressure

A

Bc of mole fraction we know Xx=Px/Ptotal

So

Px=Xx•(Ptotal)

21
Q

Partial pressure of water

A

Ptotal=PO2+PH2O

22
Q

Kinetic molecular theory

Assumes that gas molecules:

A

1-have tiny volumes compared to collective volume they occupy

2-contant random movement

3-average kinetic NRG proportional to absolute Temperature

4-engage in elastic collisions with walls of container and other gas molecules

5-act independently of other gas molecules

23
Q

Average kinetic energy

A

KEavg = 1/2m(U(rms))^2

U(rms)=root-mean-squared speed of the molecules=

Square root of (3RT/molar mass)