Chapter 5 Flashcards
(23 cards)
Properties of gas
-no shape or volume
-fits any container uniformly
-exerts pressure on surroundings
-change V with Temp and pressure
-miscible-mixes together in any proportion
-less sense than solids or liquids
Pressure formula
P=Force
———-
Area
Atmospheric pressure
Force exerted by gases surrounding earth on earths surface
Units of pressure
SI units= Newton/meter^2=1 pascal(Pa)
1atm=101 325 Pa
1atm=760mmHg=760torr
Barometer
Measures atmospheric pressure
Height of Hg column
(Gravity pulls Hg down/ atmospheric pressure pushes it up)
Boyles law
PV=constant
P=constant(1/V)
Charles law
V/T=constant
V1/T1=V2/T2
Avragadros law
Volume is directly proportional to number of moles of gas
V/n=constant
V1/n1=V2/n2
Amontons law
P/T= constant
P1/T1=P2/T2
Ideal gas law
PV=nRT
P-pressure (atm)
V-Volume (L)
n-moles
R-universal gas constant (0.08206 L•atm/K•mol
Allows calculation of gas properties when more than 1 variable is changing
Combined gas law
Combines Boyles/Charles/Avagadros/
PV/nT=constant(R)
If n is constant then
P1V1/T1=P2V2/T2
STP
Standard temp and pressure
P= 1 atm
T=273K (0.0°C)
Molar volume
V=22.4L
Density in gases
D=m/V= (pressure)(molar mass)/(ideal gas constant)(Temp)
Ideal gas constant
0.0821 L•atm/mol•K
Dalton’s law of partial pressure
Pressure depends on the total moles not the identity of the gas
∝
Means proportional to
1 side is constant of the other
Mole fraction
Ratio of number of moles of a component in a mixture to the total number of moles in a mixture
Xx=nx/ntotal=nx/n1+n2+n3…
Mole fraction in terms of pressure
N1=P1V/RT
Partial pressure
Bc of mole fraction we know Xx=Px/Ptotal
So
Px=Xx•(Ptotal)
Partial pressure of water
Ptotal=PO2+PH2O
Kinetic molecular theory
Assumes that gas molecules:
1-have tiny volumes compared to collective volume they occupy
2-contant random movement
3-average kinetic NRG proportional to absolute Temperature
4-engage in elastic collisions with walls of container and other gas molecules
5-act independently of other gas molecules
Average kinetic energy
KEavg = 1/2m(U(rms))^2
U(rms)=root-mean-squared speed of the molecules=
Square root of (3RT/molar mass)