Chapter 6 Flashcards

(34 cards)

1
Q

What is the shape and properties of group two?

A

linear, 180°, 2 bond pair and no lone pairs

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2
Q

What is the shape and properties of group 3?

A

Trigonal planar, 120°, 3 bond pairs and no lone pairs

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3
Q

What is the properties and shape of group 4?

A

Tetrahedral, 109.5°, 4 bond pairs and no lone pairs

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4
Q

What is the shape and properties of group 5?

A

Pyramidal, 107º, 3 bond pairs and one one pair

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5
Q

What is the shape and properties of group 6?

A

Non-linear, 104.5°, 2 bond pair 2 lone pair

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6
Q

Why are electrons equally spaced out?

A

Repulsion’s are equal

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7
Q

What happens to the shape it lone pairs are present?

A

Shape is distorted

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8
Q

Why is the shape distorted with the addition of lone pairs?

A

Extra repulsion is caused by lone pairs

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9
Q

How much do lone pairs push bond angle down by?

A

2.5°

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10
Q

How many bonding pairs does an octahedral have? What is the bond angle

A

6 pairs, 90°

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11
Q

What is electronegativity?

A

A measure of the tendency of an atom to attract a bonding pair of electrons in a covalent bond

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12
Q

What happens it you increase the electronegativity?

A

Increases the electrons attracted to it

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13
Q

What are the three factors affecting electronegativity?

A

Atomic charge,distance from nucleus, electron shielding

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14
Q

How does electronegativity increase in the periodic table?

A

Across the groups and up the period

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15
Q

Would the dipole be negative or positive it the atom was more electronegative than the other?

A

Negative

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16
Q

What happens to the dipole is there is a greater difference of electronegarivity?

A

Greater permanent dipole

17
Q

What is a permanent dipole?

A

The charge difference between two bonded atoms of different electronegativities

18
Q

Are symmetrical bonds polar or non polar?

19
Q

What are symmetrical molecules?

A

There are not just areas of just positive or just negative charge

20
Q

Which is the most electronegative element?

21
Q

What effect on polarity do lone pairs have?

A

Can cancel out dipoles created by bonding pairs

22
Q

What are intermolecular forces?

A

Weak interactions between dipoles of different molecules

23
Q

What are London forces? And what are they caused by?

A

Weak intermolecular forces caused by very small dipoles in molecules.

24
Q

What are factors affecting strength ?

A

The greater the number of electrons in each molecule,the larger the oscillating and induced dipoles and the greater the attractive forces between molecules

25
What is a polar molecule?
A molecule which atoms have significant differences in their electronegativity and a dipole created
26
What elements can hydrogen bonding occur?
Fluorine, nitrogen and oxygen
27
What is hydrogen bonding?
Special type of dipole-dipole interaction
28
Why does hydrogen only bond with specific atoms?
Hydrogen has a high density and F,N and O are highly electronegative
29
What is the best example of hydrogen bonding?
Water
30
What happens to water when it freezes?
The density decreases
31
What is the structure of ice and what happens to it when it melts?
Diamond structure and it will collapse
32
What happens to most simple molecular lattices (minus h20)?
They sublime, water doesn't due to the hydrogen bonds
33
What properties do water get from hydrogen bonds?
Relatively high viscosity and surface tension
34
What happens to the surface tension on q liquid if you disrupt the hydrogen bonds?
It decreases