Chapter 7 Flashcards

1
Q

The vertical distance from the midline of a wave to the peak or trough

A

Amplitude

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2
Q

The number of waves that pass through a particular point in 1 second

A

Frequency

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3
Q

The speed of a wave

A

U = lamda x v

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4
Q

Proposed that visible light consist of electromagnetic waves

A

Maxwell 1873

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5
Q

In the visible light consist of electromagnetic waves…(2 components)

A

Electric field component and magnetic field component

Perpendicular to one another

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6
Q

The emission and transmission of energy in the form of electromagnetic waves

A

Electromagnetic radiation

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7
Q

Speed of light

A

3.00x10^8 m/s

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8
Q

What we can see small part of electromagnetic spectrum

400-700 nanometer

A

Visible light

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9
Q

Electro attic radiation

A

Lamda x v =c

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10
Q

A photon has a frequency of 6.0x10^4 Hz. Convert into wavelength

A

Lamda = c/v

3.00x10^8 m/s / 6.0x10^4 Hz

Convert to nanometer

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11
Q

What did max planch (1900) discover?

A

-when solids are heated, they emitted electromagnetic radiation over a wide range of wavelength

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12
Q

Radiant energy emitted by an object at a certain temperature depends on its____

A

Wavelength

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13
Q

Energy is emitted or absorbed in discrete units called____

A

Quantum

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14
Q

Planch’s constant

A

h=6.63x10^-34 Js

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15
Q

Photoelectric effect 1905

A
  • Einstein
  • metals emit electrons when exposed to light
  • light has both wave nature and particular nature
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16
Q

A particle of light

A

Photon

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17
Q

Finger prints for atoms

A

Line spectra

-excited by a high energy discharge, the light will pass through a prism

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18
Q

Bohr’s model of the atom 1913

A
  • electrons can only have specific (quantinize) energy values
  • light is emitted as electron moves from one energy level to a lower energy level
19
Q

En=-RH(1/n^2)

What is n and R?

A

R= rydburg constant 2.18x10^-18 J

n = principal quantum number - integers (1, infinity)

20
Q

4 scenes of transitions of the hydrogen atom from higher energy levels to lower energy levels

A

E (n=1) - Lymdn
E(n=2)- balmer
E(n=3)- paschen
E(n=4)- bracket

21
Q

wavelength can’t be _____

22
Q

Why is energy quantinized?

A

De broglie (1924) reasoned that electron is both particle and wave

h/mu

23
Q

Schrodinger wave equation

A

An equation that described both the particle and wave nature of the electron

24
Q

Schrodingers equation can only be exactly solved for ___ atoms. An approximate solution is used for multi electron systems.

25
Wave function: 1. 2.
1. Energy of electrons with a given wave function | 2. (Wave function (sigh))^2 is the probability of finding electrons in a volume of space
26
Sigh is a function of 4 numbers called _____
Quantum numbers (n, l, m, ms) | m sub s
27
Quantum number n =
Distance of electron from the nucleus
28
90% of the electron density is found for the___
1s orbital
29
Quantum number l=
Angular momentum quantum number **** l=n-1
30
When n= 1 n=2 n=3 L=?
l= 0 l= 0 or 1 l=0,1 or 2
31
l=0 l=1 l=2 l=3 What orbital?
``` 0 = s orbital 1= p orbital 2= d orbital 3= f orbital ```
32
L represents ....
Shape of the volume of space that the electron occupies
33
Pauli exclusion principle
No 2 electrons in an atom can have the same 4 quantum numbers
34
Electrons with the same value of n
She'll
35
Electrons with the same values of n and l
Subshell
36
Electrons with the same values of n l and ml
Orbital
37
How many electrons can an orbital hold?
2 electron (with opposite spin)
38
"Fill up" electrons in lowest energy orbitals
Aufbau Principle
39
The most stable arrangement of electrons in Subshell is the one with the greatest number of parallel spins
Hund's rule
40
What are the possible quantum numbers for the last (outermost) electron in Cl?
N=3 L=1 Ml=-1,0,1 Ms= 1/2, -1/2
41
What is the electron configuration of Mg?
1s^2 2s^2 2p^6 3s^2 Abbreviation: [Ne] 3s^2
42
Unpaired electrons
Paramagnetic
43
All electrons paired
Diamagnetic
44
The distance between identical points on successive waves
Wavelength (lamda)