Chapter 7 Flashcards
What is a sigma bond?
When the ends of the orbitals overlap
What is a pi bond?
When the sides of the orbitals overlap
Out of a sigma and pi bond, which is stronger?
Sigma
When is a sigma and a pi bond at their strongest?
When they combine
What is a covalent bond?
Bonds forming by sharing electrons
Non metals and non metals
What are ionic bonds?
ions are held together through attraction of opposite charges
Metals and non metals
What are the exceptions to the octet rule?
- Some molecules have an odd number of valence electrons to share
- Some elements are content with fewer than four pairs of shared electrons
- more than eight va- lence electrons are shared with a central atom
What are some examples for the octet rule?
- Nitrogen contributes five valence electrons, while the two oxygen atoms bring a total of twelve.
- Boron tends to form molecules in which it is surrounded by only six valence electrons. For example, boron has just three valence electrons, and fluorine already has seven of the eight electrons it needs for stability.
- In order to use all forty-eight valence electrons, each of the fluor- ine atoms forms a single bond (one shared pair) with the central atom, sulfur. Sulfur thus shares six pairs of electrons.
What do antibonding orbitals do?
Destabilize the molocule
A chemical bond that has partially positive and partially negative ends because of unevenly shared electrons. All bonds between nonidentical atoms are polar.
Polar covalent bond
Orbitals that form when atomic orbitals combine in an unfavorable manner.
Anti bonding orbital
What does molecular residence do?
It gives the molocule the ability to move around
What is the vesper model?
Where it has two dense electrons and they are bonds and paired electrons
What is symmetrical?
Balanced
What is A-symmetrical?
Not balanced