Chapter 7 Flashcards

1
Q

What is a sigma bond?

A

When the ends of the orbitals overlap

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2
Q

What is a pi bond?

A

When the sides of the orbitals overlap

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3
Q

Out of a sigma and pi bond, which is stronger?

A

Sigma

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4
Q

When is a sigma and a pi bond at their strongest?

A

When they combine

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5
Q

What is a covalent bond?

A

Bonds forming by sharing electrons

Non metals and non metals

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6
Q

What are ionic bonds?

A

ions are held together through attraction of opposite charges
Metals and non metals

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7
Q

What are the exceptions to the octet rule?

A
  1. Some molecules have an odd number of valence electrons to share
  2. Some elements are content with fewer than four pairs of shared electrons
  3. more than eight va- lence electrons are shared with a central atom
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8
Q

What are some examples for the octet rule?

A
  1. Nitrogen contributes five valence electrons, while the two oxygen atoms bring a total of twelve.
  2. Boron tends to form molecules in which it is surrounded by only six valence electrons. For example, boron has just three valence electrons, and fluorine already has seven of the eight electrons it needs for stability.
  3. In order to use all forty-eight valence electrons, each of the fluor- ine atoms forms a single bond (one shared pair) with the central atom, sulfur. Sulfur thus shares six pairs of electrons.
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9
Q

What do antibonding orbitals do?

A

Destabilize the molocule

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10
Q

A chemical bond that has partially positive and partially negative ends because of unevenly shared electrons. All bonds between nonidentical atoms are polar.

A

Polar covalent bond

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11
Q

Orbitals that form when atomic orbitals combine in an unfavorable manner.

A

Anti bonding orbital

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12
Q

What does molecular residence do?

A

It gives the molocule the ability to move around

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13
Q

What is the vesper model?

A

Where it has two dense electrons and they are bonds and paired electrons

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14
Q

What is symmetrical?

A

Balanced

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15
Q

What is A-symmetrical?

A

Not balanced

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16
Q

Know the sigma symbol.

A

*

17
Q

What shape is always polar?

A

Bent

18
Q

What symbol is dipole moment represented by?

A

Sigma

19
Q

What shape has four atoms on a plane?

A

Trigonal planar

20
Q

Know how to draw Lewis dot structure, shape, polarity (considering and not considering the shape) of the molocule, and electronegativity.

A

*

21
Q

The vector sum of the distance between charges and the strength of the charges; a measure of all bond polarities that exist within a molecule.

A

Dipole moment

22
Q

What is the vespr theory?

A

A theory stating that because of electron-electron repulsion, the electron orbitals in molecules are arranged so that they are as far apart as possible around the central atom.

23
Q

What is the molecular orbital theory?

A

A bonding theory that suggests that the orbitals of a molecule’s atoms are replaced by totally new orbitals when a molecule forms. These orbitals, both bonding and non-bonding, are linear combinations of the atomic orbitals.

24
Q

What is the valence bond theory?

A

The concept that covalent bonds are formed when orbitals of different atoms overlap; also called the localized electron theory.

25
Q

What is the symbol that shows where electrons have shifted and points to the atom with higher electronegativity

A

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