Chapter 7-8 terms Flashcards
A hybrid bond in which an s and p orbital overlap end to end?
Sigma bond
The concept that covalent bonds are formed when orbitals of different atoms overlap; also called the localized electron theory?
Valence bond theory
A bond in which there is a side-by-side overlap of the orbitals?
Pi bond
A molecular property where, instead of oscillating between two different bond regions, the bonds take on an intermediate character?
Resonance
A bonding theory that suggests that the orbitals of a molecule’s atoms are replaced by totally new orbitals when a molecule forms. These orbitals, both bonding and non-bonding, are linear combinations of the atomic orbitals?
Molecular orbital theory
A theory stating that because of electron-electron repulsion, the electron orbitals in molecules are arranged so that they are as far apart as possible around the central atom?
valence shell electron pair repulsion (VSEPR) theory
A structural arrangement in which four areas of electron density surrounding a central atom are oriented toward the corners of a four-sided pyramid?
Tetrahedral
A structural arrangement in which three particles surrounding a central particle are oriented toward the corners of a flat triangle?
Trigonal planar
A structural arrangement in which particles are positioned in a straight line?
Linear
The process of forming new kinds of orbitals with equal energies from a combination of orbitals of different energies?
Hybridization
A structural arrangement in which three particles and an unshared electron pair surrounding a central particle are oriented toward the corners of a four-sided pyramid?
Pyramidal
A structural arrangement in which two particles are bonded to a central particle nonlinearly?
Bent
A chemical bond that has partially positive and partially negative ends because of unevenly shared electrons. All bonds between nonidentical atoms are polar?
Polar covalent bond
The vector sum of the distance between charges and the strength of the charges; a measure of all bond polarities that exist within a molecule?
Dipole moment
represent the number of electrons that an atom in a compound must gain or lose to return to its neutral state?
Oxidation numbers
covalently bonded groups of atoms that carry a charge?
Polyatomic ions
A system of naming that follows a standardized set of rules?
Nomenclature