Chapter 7 Vocab Flashcards

(40 cards)

1
Q

Electromagnetic radiation (also electromagnetic energy or radiant energy)

A

Oscillating, perpendicular electric and magnetic fields moving simultaneously through space as waves and manifested as visible light, x-rays, microwaves, radio waves, and so on.

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2
Q

Frequency (ν)

A

The number of complete waves, or cycles, that pass a given point per second, expressed in units of 1/second, or s^-1 [also called hertz (Hz)]; related inversely to wavelength.

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3
Q

Wavelength (λ)

A

The distance between any point on a wave and the corresponding point on the next wave, that is, the distance a wave travels during one cycle.

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4
Q

Speed of light (c)

A

A fundamental constant giving the speed at which electromagnetic radiation travels in a vacuum; c = 2.99792458 x 10^8 m/s.

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5
Q

Amplitude

A

The height of the crest (or depth of the trough) of a wave; related to the intensity of the energy (brightness of the light).

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6
Q

Electromagnetic spectrum

A

The continuum of radiant energy arranged in order of increasing wavelength.

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7
Q

Ultraviolet (UV)

A

Radiation in the region of the electromagnetic spectrum between the visible and the x-ray regions.

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8
Q

Infrared (IR)

A

The region of the electromagnetic spectrum between the microwave and visible regions.

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9
Q

Refraction

A

A phenomenon in which a wave changes its speed and therefore its direction as it passes through a phase boundary into a different medium.

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10
Q

Diffraction

A

The phenomenon in which a wave striking the edge of an object bends around it. A wave passing through a slit as wide as its wavelength forms a circular wave.

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11
Q

Quantum number

A

A number that specifies a property of an orbital or an electron.

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12
Q

Planck’s constant (h)

A

A proportionality constant relation the energy and frequency of a photon, equal to 6.62607015 x 10^-34 J⋅s.

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13
Q

Quantum

A

A packet of energy equal to hν. The smallest quantity of energy that can be emitted or absorbed.

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14
Q

Photoelectric effect

A

The observation that, when monochromatic light of sufficient frequency shines on a metal, an electric current is produced.

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15
Q

Photon

A

A quantum of electromagnetic radiation.

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16
Q

Line spectrum

A

A series of separated lines of different colors representing photons whose wavelengths are characteristic of an element (see also emission spectrum).

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17
Q

Stationary state

A

In the Bohr model, one of the allowable energy levels of the atom in which it does not release or absorb energy.

18
Q

Ground state

A

The electron configuration of an atom (or ion or molecule) that is lowest in energy.

19
Q

Excited state

A

Any electron configuration of an atom (or ion or molecule) others than the lowest energy (ground) state.

20
Q

de Broglie wavelength

A

The wavelength of a moving particle obtained from the de Broglie equation: λ = h/mu.

21
Q

Wave-particle duality

A

The principle stating that both matter and energy have wavelike and particle-like properties.

22
Q

Uncertainty principle

A

The principle stated by Heisenberg that it is impossible to know simultaneously the exact position and velocity of a particle; the principle becomes important only for particles of very small mass.

23
Q

Quantum mechanics

A

The branch of physics that examines the wave nature of objects on the atomic scale.

24
Q

Schrödinger equation

A

An equation that describes how the electron matter-wave changes in space around the nucleus. Solutions of the equation provide energy states associated with the atomic orbitals.

25
Wave function (ψ)
A mathematical description of the electron’s matter-wave in three dimensions.
26
Atomic orbital
The wave function of an electron in an atom. The term is used qualitatively to mean the region of space in which there is a high probability of finding the electron.
27
Electron cloud depiction
An imaginary representation of an electron’s rapidly changing position around the nucleus over time.
28
Electron density diagram (also electron probability density diagram)
The pictorial representation for a given energy sub level of the quantity ψ^2 (the probability density of the electron lying within a particular tiny volume) as a function of r (distance from the nucleus).
29
Radial probability distribution plot
The graphic depiction of the total probability distribution (sum of ψ^2) of an electron in the region near the nucleus.
30
Probability contour
A shape that defines the volume around an atomic nucleus within which an electron spends a given percentage of its time.
31
Principle quantum number (n)
A positive integer that specifies the energy and relative size of an atomic orbital; a number that specifies an energy level in an atom.
32
Angular momentum quantum number (l)
An integer from 0 to n-1 that is related to the shape of an atomic orbital.
33
Magnetic quantum number (ml)
An integer from -l through 0 to +l that specifies the orientation of an atomic orbital in the three-dimensional space about the nucleus.
34
Level (also shell)
A specific energy state of an atom given by the principal quantum number n.
35
Sublevel (also subshell)
An energy substrate of an atom within a level. Given by the n and l values, the sublevel designates the size and shape of the atomic orbitals.
36
S orbital
An atomic orbital with l = 0.
37
Node
A region of an orbital where the probability of finding the electron is zero.
38
P orbital
An atomic orbital with l = 1.
39
D orbital
An atomic orbital with l = 2.
40
F orbital
An atomic orbital with l = 3.