Chapter 8 Flashcards
(18 cards)
Linear
2 bonding 0 non bonding
180°
Triganol planar
3 non bonding 0 non bonding
120°
Tetrahedral
4 bonding 0 non bonding
109.5°
Triganol bypramidal
3 bonding 1 non bonding
107°
Bent
2 bonding 0 non bonding
120° 90°
Octahedral
6 bonding 0 non bonding
90°
Hydrogen is NOT a _________
metal
Helium is a _______
Noble has
how many electrons does a covalent bond have ?
2 electrons
Lewis structures
•1916 •electron dot structures show valence electrons •used for "A" groups only [ ] - ion No [ ] then no ion
Lewis dot diagrams
•used only for molecules
•when drawing them
1.sum of of valence electrons
2. Write symbols/atoms in order
3. Complete octets of atoms bonded to central atoms
4. When you don’t have enough electrons, to give to an central, an octet tries multiple bonds
VSEPR theory
• Valence Shell Electron Pair Repulsion
• molecules adjust shape to decrease electron repulsion
• geometry determined by counting domains
1. Bonding pair
2. Nonbonding
Bond length & strength
•distance between atoms decreases as number of shared electrons increases
N-N N=N N(3 bonds)N
1.47 A. 1.24 A. 1.10 A
Triple bonds
- smallest,more stable, shortest
- Very stable
- Earths atmosphere is 78% N2 due to its stability
Nitrogen fixation occurs in_______________
Bacteria in the root modules of legumes (beans)
Intermolecular forces:
Ion-dipole forces
•interaction between an ion and a dipole
• opposites attract
• water has the ability to go and get ions (only if soluable)
• salt dissolved in water
• STRONGEST OF ALL
Vanderwalls forces
- dipole-dipole forces
- polar molecules
- intermediate strengths (not strong, not weak)
- most polar, bigger attraction
- exists in liquids
London dispersion forces (LDF)
• constant random motion of electrons about atom creates temporary positive and negative charges.
• Very weak (weakest) –> because poles are temporary
•Instintanious dipole induces dipole
-liquid N2 -196° C (77K)
• all molecules exhibit dispersion forces
•strengths increase w/ atomic size
-large electron clouds are polarizable
• trends in halogens