Chapter 8- Chemical Bonding Flashcards

(51 cards)

1
Q

Ionic

A

Metals and nonmetals

Unfair sharing of electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Covalent

A

Nonmetals and nonmetals
Fair sharing of electrons
Can be polar or nonpolar

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Metallic

A

E cloud bonds atoms

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Octet rule

A

Atoms tend to lose or gain until they are surrounded by 8 electrons except H which needs two

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Polar bonds

A

Covalent bonds in which electrons are shared unequally die to the differences in the elements electronegativities

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Polar molecule (dipole)

A

A molecule containing a polar bond which results in an uneven distribution of electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Dipole moment

A

Measurement of the magnitude of dipole

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Reasonable structures

A

Molecules with more than one plausible structure

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Lattice energy (Eel)

A

Energy required to completely separate 1 mol of an ionic crystal into its gaseous ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

All ionic compounds

A

Are solid and exist as a crystal lattice

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Ionic bonds are ______ than covalent bonds

A

Stronger

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Formula for lattice energy

A

Eel = (constant times charges of ions) / distance between nuclei

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Lattice energy

A

All about charge and attraction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Formal charge

A

The charge that an atom in a molecule would have if all of its bonding electron pairs were shared equally between atoms
(Allows us to predict correct form of a molecule)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Formal charge adds up to

A

The charge of the ion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Halogens only form

A

Single bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

Anything form the throw period down can

A

Hybridize

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

Heat of reaction

A

Bonds broken-bonds formed

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

VSEPR

A

Valance shell electron pair repulsion theory

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

Electron pairs on a central atom

A

Bonded or unbounded will repel, thus creating the molecules shape

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

Electron domains

A

The areas where the electrons are likely to be located

22
Q

Electron domain geometry

A

Shape created by the electron domains

23
Q

Molecular geometry

A

The shape created by the arrangement of atoms

24
Q

Shape of two electron domains

A

Linear (180 degrees)

25
Shape of three electron domains
``` Trigonal planar (120) Bent(120) (one unbounded pair) ```
26
Shape of four electron domains
``` Tetra hedral (109) Trigonal pyramidal (107) Bent (two unbounded electrons) (104) ```
27
Tetrahedral
109
28
Trigonal pyramidal
107
29
Bent (one unbounded electron pair)
120
30
Bent (two unbounded electron pairs)
104
31
Trifocals planar
120
32
How does a bond affect a molecules polarity
A polar bond "bond dipole" is a vector quantity. Therefore it has magnitude and direction
33
Bonding site
Orbital with only one electron in it
34
Valance bond theory
Covalent bonds are formed by overlapping atomic orbitals which contain electrons
35
Does orbital overlap happen in polyatomic molecules?
Yes but the atomic orbitals (s,p,d) mix to form a hybrid orbital
36
Linear
Sp
37
Trifocals planar
Sp2
38
Tetrahedral
Sp3
39
Covalent bonds can be classified as
Sigma or pi bonds
40
Sigma bond
End to end overlap of atomic orbitals
41
The electron density of sigma bonds
Is concentrated along a line that connects the nuclei
42
Pi bond
A side by side overlap of Unhybridized atomic orbitals
43
Electron density of pi bonds
Is concentrated above and below a line that connects the nuclei
44
Single bond
Sigma bond
45
Double bond
One sigma | One pi
46
Triple bond
One sigma | Two pis
47
Electronic geometry may be different from molecular geometry because
The electronic geometry refers to how the electrons are arranged, but the molecular geometry indicates the net shows of the molcule
48
VSEPR theory is based on
Minimization of repulsion among valance electron pairs
49
The central atom in compounds with square planar geometric always abet the octet rule
True
50
Large electronegativities difference affects molecular properties
By making boss stronger and shorter Makes bonds highly polar Makes molecule highly polar if molecular geometry permits
51
Metallic bond
Metals and metals | Electron clouds around atom