chapter 9 (thermochemistry) Flashcards

1
Q

thermochemistry

A

the study of chem and energy

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2
Q

energy

A

the capacity to do work or heat

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3
Q

heatq

A

the flow of energy caused by a temp difference

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4
Q

law of conservation of energy

A

energy can not be created or destroyed, jsut change forms

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5
Q

first law of thermo

A

total energy of the universe is constant

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6
Q

internal energy (state function)

A

sum of kinetic and potential energies

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7
Q

state function

A

jsut depends of the current state, not how it got there

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8
Q

specific heat capacity

A

the amount of energy required to raise 1 gram of X 1degree celcius

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9
Q

q(amount of heat) in J=

A

mcAt

mass x specific heat x temp change

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10
Q

delta E

A

E final -E intial

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11
Q

Enthalpy H

A

the sum of internal energy and the product of its pressure and volume
H=E+PV

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12
Q

delta H

A

deltaH=deltaE+pDeltaV

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13
Q

endothermic

A

absorbs heat from the surroundings
colder
gains potential energu

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14
Q

exothermic

A

gives off heat to the surrounding
hotter
releases potential energy to the masses

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15
Q

does an endothermic reaction have a positive or negative H

A

positive

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16
Q

does an exothermic reaction have a positive or negative H

A

negative

17
Q

quantifying delta H

A

the amount to heat absorbed or evolved in the reaction under conditions of constant pressure

18
Q

is it exothermic or endothermic

  1. sweat evaporating from skin
  2. water freexing in freezer
  3. wood burning in fire
A
  1. endothermic(cools the sin)
  2. exothermic(the water releases heat and cools down(freezer removes this heat))
  3. releases heat( exothermic)
19
Q

given equation,mass of one thing, heat of reaction, find heat evolved in reaction

A

find the mass in moles, then use the heat of reaction to turn it into energy with stoich

20
Q

how to find equilibrium temperature

A

use mcat and set the heat equal to eachother for both substances

21
Q

determining enthalpies from bond energies

A

^rxn = sum(bonds broken) -sum(bonds formed )

22
Q

define exothermic with bonds

A

weak bonds break and strong ones form

23
Q

define endothermic with bonds

A

strong bonds break and weak ones form