chem Flashcards by Alex Osu!

Q

Cond Claisen

A

LDA, 25/-78, THF

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Q

Claisen Schmidtf

A

LDA, 25/-78, THF

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Q

Cond aldolica

A

LDA, 25/-78, THF

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Q

Natte

A

LDA, 25/-78, THF

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Q

Deickmann

A

LDA, 25/-78, THF

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Q

Sintesi Acetica

A

EtO- + calore

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Q

Sintesi Malonica

A

EtO- + calore

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Q

Base di Schiff

A

H+,H2O

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Q

Stork

A

H+,H2O

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Q

Knoevernagel

A

BuNH2

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Q

Mannich

A

HCHO, Ammina secondaria

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Q

Sir Robert Robinson Tropinone

A

H+,H2O, Calore

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Q

Anellazione di Robinson

A

Base Acide

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Q

TSHibibabin

A

NaNH2, NH3

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Q

Se Piridina

A

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Q

Hantzsch

A

H2O

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Q

Scramp

A

H+, DDQ

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Q

Paul-Knorr

A

NH3, P2O5

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Q

Fisher (indolo)

A

H+

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Q

Fisher Glucosio

A

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Q

Kiliam Fisher

A

HCN, Ba(OH)2, Na(Hg), o , HCN, Pd/BaSO4, H+

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Q

Degrqadaziojne di Wohl

A

NH2OH, Ac2O exc, Base,

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Q

Degradazione di Ruff

A

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Q

Hell Volhard Zelensky

A

PBr3, Br2

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Immido malonati

EtO-, Br2, Potassioftalimmide, calore

Strecker

HCN, H+

Glicina

Alanina

Cisteina

Glutammina

Fenil alanina

Estere benzilico

basico neutro e acido trietilammina

BOC

Base, rilascio CF3CO2H trietilammina

Fmoc

rilascio cond basiche trietilammina

Stirene

P iso Ninidrina

Acido oleico

Acido linoleico

Acido linolenico

Sasponificazione

Na2CO3--------> NaOH

Fosfolipido

FosfatidilColina

Non saponificabili

Terpeni Trombossani prostaglandine Leucotrieni

Terpeni

Adenina`

Guanina

Citosina

Timina

Uracile

trasp. cope

trasp. Claisen

Sabatier

H2, Pd/Pt/Rh

Rid. Benzene

H2, Pd, 100Atm

Cat. Lindlar

CaCO3, Pd, Chinolina, Pb(OAc)2

Wilkinson

H2, ClRh(PPh3)3

Rid. diazene

Per diazene, idrazina, Cu2+ O2, riduziojne idrazina,O2,Cu2+

LiAlH4

BH3

Rosemond

H20, SOCl2, Lindlar, H2

Cannizzaro

OH-

Clark Eshuweiien

HCHO, HCOOH

Bourandt blank

Na, EtOh

Napinepen

Na, EtOH

Brack

Li/Na/K, NH3 Liq

Di idrossi accoppiamento

Mg(Hg), THF, H+

Birch (alchino a alchene trans)

Li, NH3 liq

Pinacolo e trasposizione pinacolica

Prelog

4Na, Xilene, H+

Clemmensen

Zn(Hg), HCl 37%

WolfKishner

idrazina, KOH 20%, 1,2- etanolo 200gr

Caglioti Vincenzo

toluenesolfonil idrazide, H+, NaBH4

Riducente di Raney Ni/Ra`

Permanganato

KMnO4, 0-5C

Osmio

Ox= Ba(ClO3),tBuOOH, OsO4=catalizzatore

epossidi

Perossiadidi, e doppi legami, o perossido, e stessa molecola per l'anellazione di robinson

Epossidazione col vanadio

tBuOOH,VO(AcAc)

Epossido, col titanio

tBuOOH,Ti(OCH(CH3)2)

Cromo

HCrO4-, H2), o uso PCC (piridinio clorocromato)

MnO2 | Uso per ossidare alcoli allilici e benzilici

Maffat

DMSO, PCC, dicicloesilimmide

N cloro succinimmide

dimetil solfuro

TEMPO fa da mediatore

Riduzione Ammide

LiAlH4

Apertura Epossido

Epossido con Ozono

Epossido con Ozono

Chetoni con KMnO4

MnO4-, IO4-