chem quiz 2 Flashcards

(56 cards)

1
Q

variable for entropy

A

“S”

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2
Q

which state of matter has the highest entropy

A

gas

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3
Q

what is related to the freedom of motion of the particles

A

entropy

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4
Q

does a solution, pure solute, or pure solvent have the highest entropy

A

solution

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5
Q

systems change toward (lower/higher) entropy

A

higher entropy

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6
Q

systems change toward (lower/higher) enthalpy

A

lower enthalpy

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7
Q

contains the maximum amount of dissolved solute at a given temperature in the presence of undissolved solute

A

saturated solution

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8
Q

in equilibrium with dissolved solute

A

undissolved solute

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9
Q

contains less than the equilibrium concentration of dissolved solute

A

unsaturated solution

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10
Q

solids become (more/less) soluble at higher temperatures

A

more

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11
Q

gasses become (more/less) soluble at higher temperatures

A

less

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12
Q

as pressure increases, gas solubility (increases/decreases)

A

increases

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13
Q

the solubility of a gas is (directly/inversely) proportional to the partial pressure of the gas above the solution

A

directly

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14
Q

the pressure that must be applied to prevent the net flow of solvent

A

osmotic pressure

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15
Q

properties that depend on the number of solute particles, not their chemical identity

A

colligative properties

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16
Q

the vapor pressure of a solution containing a nonvolatile nonelectrolyte is always (lower/higher) than the vapor pressure of the pure solvent

A

lower

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17
Q

Raoult’s law states that the vapor pressure of the solvent is (directly/inversely) proportional to the mole fraction of the solvent present

A

directly

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18
Q

the boiling point elevation is proportional to the (molality/molarity) of the solution

A

molality

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19
Q

for a volatile nonelectrolyte, the vapor of the solution contains…

A

both solute and solvent

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20
Q

the study of reaction rates and the factors that affect them

A

chemical kinetics

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21
Q

the change in the concentrations of reactants or products as a function of time

A

reaction rate

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22
Q

rate =

A

change of concentration / change in time

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23
Q

mol / L * s

24
Q

mol L -1 s -1

25
1/s
1st order
26
s -1
1st order
27
L / mol *s
2nd order
28
L mol -1 s -1
2nd order
29
L^2 / mol^2 * s
3rd order
30
L^2 mol -2 s-1
3rd order
31
integrated rate law 1st order rearranged
ln [A]t = -kt + ln [A]0
32
integrated rate law 2nd order rearranged
1/[A]t - 1/[A]0 = kt
33
integrated rate law 1/2 life rearranged
[A]t - [A]0 = -kt
34
steps for finding reaction orders with experimental data (in terms of [A])
1. find which row [B] has a consistent concentration 2. divide one concentration over the matching time 3. divide second concentration by matching time 4. find out which power will take you from first answer to second
35
ammonium
NH 3+
36
hydronium
H3O+
37
hydroxide
OH-
38
nitrite
NO2 -
39
nitrate
NO3 -
40
carbonate
CO3 2-
41
hydrogen carbonate
HCO 3-
42
phosphate
PO4 3-
43
sulfite
SO3 2-
44
sulfate
SO4 2-
45
(T/F) the greater the energy of activation, the slower the reaction will be
true
46
(T/F) colligative properties of solutions depend on the number of solute particles present in the solution
true
47
(T/F) dissolving a solute in a solvent lowers the vapor pressure of the resulting solution compared to the pure
true
48
(T/F) osmotic pressure is the force required to prevent the movement of solvent molecules through a semi-permeable membrane
true
49
(T/F) the rate law can be readily predicted from the balanced chemical equation of a reaction
false
50
(T/F) the half life of a first-order reaction remains constant regardless of the initial concentration of the reactant
true
51
i of sodium sulfate
3
52
does i increase with osmotic pressure
yes
53
what is the order of a reaction when the plotted line is linear
first order
54
molarity formula
moles of solute / liters of soln
55
molality formula
moles of solute / kg of solvent
56