Chemical Bonding Flashcards

Lessson 2 (37 cards)

1
Q

Ionic bonding occurs between atoms with large differences in their tendencies to lose or gain electrons. Such differences occur between reactive metals (Grps 1A and 2A) and nonmetals (Grp 7A and the top of Grp 6A)

A. Nonmetal with nonmetal: electron sharing and covalent bonding
B. Metal with nonmetal: electron transfer and ionic bonding
C. Metal with metal: electron pooling and metallic bonding

A

A. Metal with nonmetal: electron transfer and ionic bonding

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2
Q

A _____ (with low ionization energy or IE) loses its one or two valence electrons, and a nonmetal atom (with highly negative electron affinity or EA) gains the electron/s.

A. Acid Atom
B. Salt Atom
C. nonmetal atom
D. metal atom

A

D. metal atom

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3
Q

_____________________________ occurs, and each atom forms an ion with a noble gas electron configuration. The electrostatic attractions between these positive ions (cations) and negative ions (anions) draw them into a three-dimensional array to form an ionic solid.

A. Electron transfer from nonmetal to metal
B. Electron configuration from nonmetal to metal
C. Electron transfer from metal to nonmetal
D. Electron configuration from metal to nonmetal

A

C. Electron transfer from metal to nonmetal

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4
Q

Note that the chemical formula of an ionic compound is the ______ because it gives the cation-anion ratio

A. empirical formula
B. formula
C. molecular formula
D. molecule

A

A. empirical formula

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5
Q

____ are written and named with the cation or positive ion first followed by the anion or negative ion.

A. Ionic mixture
B. Ionic bonding
C. Ionic formula
D. Ionic compounds

A

D. Ionic compounds

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6
Q

When two atoms differ little, or not at all, in their tendencies to lose or gain electrons, we observe electron sharing and covalent bonding, which occurs most commonly between nonmetal atoms, as in O─H in H2O.

A. Nonmetal with nonmetal: electron sharing and covalent bonding
B. Metal with nonmetal: electron transfer and ionic bonding
C. Metal with metal: electron pooling and metallic bonding

A

A. Nonmetal with nonmetal: electron sharing and covalent bonding

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7
Q

Note that the chemical formula of a covalent compound is the _____ because it gives the actual numbers of atoms in each molecule.

A. empirical formula
B. formula
C. molecular formula
D. molecule

A

C. molecular formula

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8
Q

Metal atoms are relatively large, and their few outer electrons are well-shielded by filled inner levels (core electrons). Thus, they lose outer electrons easily (low ionization energy or IE) and do not gain them readily (slightly negative or positive electron affinity or EA). These properties lead metal atoms to share their valence electrons, but not by covalent bonding.

A. Nonmetal with nonmetal: electron sharing and covalent bonding
B. Metal with nonmetal: electron transfer and ionic bonding
C. Metal with metal: electron pooling and metallic bonding

A

C. Metal with metal: electron pooling and metallic bonding

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9
Q

Unlike the localized electrons in covalent bonding, electrons in ____ are delocalized, moving freely throughout the entire piece of the metal.

A. ionic bonding
B. ionic formula
C. metallic bonding
D. metallic formula

A

C. metallic bonding

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10
Q

gather together

a. loop/looping
b. pool/pooling
c. delocalized
d. Localized

A

b. pool/pooling

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11
Q

just in one place

a. loop/looping
b. pool/pooling
c. delocalized
d. Localized

A

d. Localized

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12
Q

can travel and move freely

a. loop/looping
b. pool/pooling
c. delocalized
d. Localized

A

c. delocalized

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13
Q

In ______________, the element symbol represents the nucleus and inner electrons, and dots around the symbol represent the valence electrons. Note that the pattern of dots is the same for elements within a group.

A. the Octet Rule
B. the Polarity
C. the Covalent
D. the Lewis electron-dot symbol

A

D. the Lewis electron-dot symbol

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14
Q

For a metal, the total number of dots is the number of electrons an atom loses to form a ____

A. polar bond
B. cation (+ ion)
C. nonpolar bond
D. anion (- ion)

A

B. cation (+ ion)

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15
Q

For a nonmetal, the number of unpaired dots equals either the number of electrons an atom gains to form an______ or the number it shares to form covalent bonds.

A. polar bond
B. cation (+ ion)
C. nonpolar bond
D. anion (- ion)

A

D. anion (- ion)

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16
Q

when atoms bond, they lose, gain, or share electrons to attain a filled outer level of eight electrons (or two, for H and Li).

A. Octet Rule
B. Polarity
C. Covalent
D. Lewis electron-dot symbol

A

A. Octet Rule

17
Q

formed due to the unequal electron sharing.

A. polar bond
B. cation (+ ion)
C. nonpolar bond
D. anion (- ion)

A

A. polar bond

18
Q

formed due to the equal electron sharing

A. polar bond
B. cation (+ ion)
C. nonpolar bond
D. anion (- ion)

A

C. nonpolar bond

19
Q

refers to the number of electron pairs being shared by a given pair of atoms

A. BOND ANGLE
B. BOND ORDER
C. BOND LENGTH
D. BOND ENERGY

A

B. BOND ORDER

20
Q

The most common bond consists of one bonding pair of electrons. Thus, a single bond has a bond order of 1.

A. Single bond
B. Double bond
C. Triple Bond
D. Bond

A

A. Single bond

21
Q

consists of two bonding electron pairs, four electrons are shared between two atoms, so the bond order is 2. Examples are O═O or O2

A. Single bond
B. Double bond
C. Triple Bond
D. Bond

A

B. Double Bond

22
Q

consists of three shared pairs; two atoms have six electrons, so the bond order is 3. Examples are N≡N or N2

A. Single bond
B. Double bond
C. Triple Bond
D. Bond

A

C. Triple bond

23
Q

the energy needed to overcome this attraction and is defined as the standard enthalpy change for breaking the bond in 1 mol of gaseous molecules.

A. BOND ANGLE
B. BOND ORDER
C. BOND LENGTH
D. BOND ENERGY

A

D. BOND ENERGY

24
Q

the distance between the nuclei of two bonded atoms.

A. BOND ANGLE
B. BOND ORDER
C. BOND LENGTH
C. HYBRIDIZATION

A

C. BOND LENGTH

25
a _______ results in a shorter bond length and a higher bond energy or a stronger bond. A. significant bond order B. large bond order C. stronger bond order D. higher bond order
D. higher bond order
26
the angle formed by the nuclei of surrounding atoms with the nucleus of the central atom at the vertex. A. BOND ANGLE B. BOND ORDER C. BOND LENGTH C. HYBRIDIZATION
A. BOND ANGLE
27
Its basic principle is that, to minimize repulsions, each group of valence electrons around a central atom is located as far as possible from the others. A. Valence-electron Pair Repulsion (VEPR) Theory B. Valence-Shell Electron-Pair Repulsion (VSEPR) Theory C. Valence-Shell Electron-Polar Repulsion (VSEPR) Theory D. Valence-Shell Energy-Pair Repulsion (VSEPR) Theory
B. Valence-Shell Electron-Pair Repulsion (VSEPR) Theory
28
A ______ of electron is any number that occupies a localized region around an atom: single bond, double bond, triple bond, lone pair, or even lone electron. A. group B. bond C. configuration D. geometry
A. group
29
This is the three-dimensional arrangement of nuclei joined by the bonding groups. A. Molecular Shape or Configuration B. Molecular Shape or Arrangement C. Molecular Shape or Geometry D. Molecular Shape or Group
C. Molecular Shape or Geometry
30
Molecular shape with two electron groups A. Tetrahedral Arrangement B. Octahedral Arrangement C. Linear Arrangement D. Trigonal Planar Arrangement E. Trigonal Bipyramidial Arrangement
C. Linear Arrangement
31
_____________ attached to a central atom point in opposite directions (AX2). This linear arrangement of electron groups in a molecule with a linear shape and a bond angle of 180°. A. Four electron groups B. One electron groups C. Seven electron groups D. Two electron groups
D. Two electron groups
32
Molecular shapes with four electron groups A. Tetrahedral Arrangement B. Octahedral Arrangement C. Linear Arrangement D. Trigonal Planar Arrangement E. Trigonal Bipyramidial Arrangement
A. Tetrahedral Arrangement
33
In tetrahedral arrangement, the four electron groups lie at the corners of a tetrahedron, a polyhedron with four faces made of equilateral triangles, giving bond angles of______ A. 180° B. 110° C. 109.6° D. 90°
109.5°
34
Molecular shapes with five electron groups A. Tetrahedral Arrangement B. Octahedral Arrangement C. Linear Arrangement D. Trigonal Planar Arrangement E. Trigonal Bipyramidial Arrangement
E. Trigonal Bipyramidal Arrangement
35
Five mutually repelling ______ form the trigonal bipyramidal arrangement, in which two trigonal pyramids share a common base. A. electron configuration B. electron formula C. electron molecule D. electron groups
D. electron groups
36
Molecular Shapes with six electron groups A. Tetrahedral Arrangement B. Octahedral Arrangement C. Linear Arrangement D. Trigonal Planar Arrangement E. Trigonal Bipyramidial Arrangement
B. Octahedral Arrangement
37
_________ form the octahedral arrangement. A. Ten electron groups B. Eight electron groups C. Seven electron groups D. Six electron groups
D. Six electron groups