Chemical Changes Flashcards

(77 cards)

1
Q

OIL RIG

A

Oxidation is loss of electrons. Reduction is gain of electrons

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2
Q

Where do metals go to?

A

Cathode

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3
Q

Where do non metals go to?

A

Anode

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4
Q

What charge is the anode?

A

Positive

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5
Q

What charge is the cathode?

A

Negative

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6
Q

What is the electrolyte?

A

Molten/ dissolved ionic compound where lots of ions float.

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7
Q

What is present when a lighted splint pops?

A

Hydrogen

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8
Q

What is present when a splint relights?

A

Oxygen

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9
Q

What is present when damp blue litmus paper bleaches?

A

Chlorine

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10
Q

What does native mean? Give an example

A

When something is found naturally and pure - they don’t need to be extracted e.g gold/silver

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11
Q

Characteristics of a giant ionic lattice

A
  • V high melting points - lots of energy to overcome strong electrostatic force of attraction
  • Brittle - Break easily due to repulsion (like charges repel)
  • Conduct electricity when they are dissolved/molten as ions can move
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12
Q

Ionic Formula

What charge is an ionic compound, why?

A

Neutral because the charges cancel each other out

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13
Q

Where does reduction happen?

A

Cathode - gain electrons

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14
Q

Where does oxidation happen?

A

Anode - lose electrons

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15
Q

What state should an element/compound be in to split up in ionic equations?

A

Aqueous

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16
Q

Which is easier to discharge, less or more reactive?

A

Less reactive

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17
Q

+Ions - What is the rule for what is discharged at the cathode?

A

Metals of lower reactivity > hydrogen
Metals of higher reactivity < hydrogen

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18
Q

-Ions - What is the rule for what is discharged at the anode?

A

Halide ions (Group 7) > oxygen
Other ions (e.g SO4) < oxygen

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19
Q

How can you measure the pH of a solution?

A
  • pH probe
  • Universal indicator
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20
Q

Reaction for neutralisation (word)

A

Acid + Alkali -> Salt + Water

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21
Q

Reaction for neutralisation (symbol) include state symbols

A

H⁺₍ₐq₎+OH⁻₍ₐq₎ –> H₂O₍ₗ₎

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22
Q

What are titrations and what do they do?

A

Method of analysing concentrations of solutions, tells you exactly how much acid/alkali is needed to neutralise

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23
Q

8 steps

Explain the steps for titrations

A
  1. Use pipette and pipette filler and set a volume of alkali to a conical flask with 2/3 drops of indicator
  2. Use a funnel and fill a burette with acid of known concentration - BELOW EYE LEVEL
  3. Record acid level in burette
  4. Add acid to alkali a bit at a time - give conical flash regular swirls
  5. Go slowly when you think it’s near the end-point (colour change)
  6. Record final volume of acid in burette
  7. Repeat
  8. Calculate mean ignoring anamolies
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24
Q

Why should you repeat titrations?

A

The first reading is a rough reading - gives you an idea of where the solution changes colour. Repeat the whole thing a few times to get the same answer

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25
By what factor does the concentration of H⁺ increase when you go down the pH scale?
10
26
# 5 Steps Soluble salts practical
1. Gently warm dilute acid using a Bunsen Burner 2. Add insoluble base to acid a bit at a time, until no more reacts (add excess so all acid reacts - excesss sinks to base) 3. Filter out excess solid to get the salt solution 4. Gently heat the solution using a water bath to evaporate water (make it more concentrated) and then stop heating and let it cool 5. Crystals form which can be filtered out and then dried - crystallisation
27
Electrolysis Practical
1. Pour solution into beaker 2. Place petri dish over beaker 3. Insert carbon graphite rods into each hole in petri dish 4. Electrodes shouldn't touch each other or else it will produce a short-circuit 5. Attach crocidle leads to rods 6. Connect rods to terminals of a low-voltage power supply (4V) 7. Check for hydrogen (squeaky pop), chlorine (blue litmus paper bleaches)
28
What is cryolite?
Aluminium compound with lower melting point than aluminium oxide - reduces cost
29
Where is alumnium extracted from?
The ore bauxite by electrolysis
30
How can we test for metal hydroxide?
Litmus paper turns blue OR universal indicator turns purple
31
What is a use of chlorine?
To make bleach
32
Why should carbon anodes be replaced regularly?
Oxygen produced at hot anodes reacts with carbon to produce carbon dioxide that burns away anodes
33
What happens when iron reacts with copper sulfate?
Copper turns brown and solution turns pale green
34
In electrolysis, which direction do the electron travel?
Anode to cathode
35
Why is electrolysis expensive, 2 reasons?
* Melting compounds like AlO2 needs a lot of energy * Lot of energy is needed to produce the electric current
36
Cathode half equation for copper sulfate (aq)
Cu²⁺ + 2e⁻ -> Cu
37
Anode half equation for copper sulfate (aq)
4OH⁻ -> O₂ + 2H₂O + 4e⁻
38
Formula for calcium carbonate
CaCO3
39
Formula for sodium hydroxide
NaOH
40
Formula for sulfuric acid
H2SO4
41
Formula for nitric acid
HNO3
42
What does litmus paper turn into in acidic and alkaline solutions?
Acidic = red alkaline = blue
43
What does phenolphthalein turn into in acidic and alkaline solutions?
Acidic = colourless Alkaline = pink
44
What does methyl orange turn into in acidic and alkaline solutions?
Acidic = red Alkaline = yellow
45
true or false? The dissociation of weak acids is a reversible reaction, which means that the products can react together to reform the acid.
true
46
For a weak acid, does the position of equilibrium lie to the left or the right?
left
47
What are strong acids?
* Ionise completely in water *
48
What are weak acids?
* They do not fully ionise in solution * Only small prop of acid particles dissociate to release hydrogen ions
49
What is important about the ionisation of weak acid?
Its reversible, which sets up an equilibrium between undissociated and dissociated aicd since only a few acid particles release H ions, equilibrium lies on the left
50
Are strong acids more reactive than weak acids of the same conc.? Why?
Yes, if the conc H ions is higher, the rate of reaction will be faster
51
What is acid strength?
Tells you what prop. of the acid molecules ionise in water
52
What is acid conc?
Tells you how much acid there is in a certain volume of water
53
Acid + metal oxide =
salt + water
54
acid + metal hydroxide =
salt + water
55
acid + carbonate
salt + water + carbon dioxide
56
Reactivity series
* Potassium * Sodium * Lithium * Calcium * Magneisum * Carbon * ZInc * Iron * Hydrogen * Copper
57
Acid + Metal
Salt + hydrogen
58
How can you measure the reactivity of metals by measuring what?
* Number of bubbles * Temp change - most reactive = most heat * Make sure it has the same mass/sa
59
metal + water
metal hydroxide + hydrogen
60
What metals dont react with water
zinc, iron, cu
61
Do metals react more violently with water or acid?
acid
62
Why do we find pure gold in the ground, but not pure iron?
* Gold is unreactive, so doesnt react with other elements * Iron is reactive enough to react with oxyen so is oxidised to iron oxide
63
What happens when sodium reacts with chlorine>
Flame and solid forms
64
Key points to add in a titration method
* calculate mean * read volume from bottom of meniscus * use pipette to measure volume of acid * rough titration to find approx end point * methyl orange - permanently turns yellow - keep swirling
65
controls in an electrlyte solution
* volume * concentration * ions
66
why is it important to replace the anode
* anode made out of carbon which reacts with oxygen * causes anodes to burn away * and co2 to be produced
67
how is hydrogen?
explsoive
68
can water as a product conduct electricity and why?
no - covalent bond
69
how is concentration related to pH?
more acid in the same volume - higher conc
70
why is it hard to separate Mg if it is used to reduce Silicon as products?
they are both solids
71
how can you increase accuracy in titrations?
repeat and calc a mean + swirl + use a white tile
72
Some copper fell off the electrode, how would you measure its mass?
1. filter mixture 2. wash + dry copper 3. weight cu collected 4. add to the increase in mass of electrode
73
why would the colour fade after electrolysis of a solution?
solution is less concentrated
74
Using avogadros constant, what is the formula for calculating the number of atoms using moles and mr and the constant?
Moles/Mr X Avogadros constant
75
Diff between process in electrolysis and chemical cell
electrolysis: uses electricity to produce chem reaction chemical cell = uses chem reaction to produce electricity
76
How is a line directionally proportional?
straight line that passes through the origin
77
When do you use FC anad distillation?
fc - similar BP distillation - very diff bp