Chemical Changes Flashcards

(44 cards)

1
Q

Electrolysis

Why would you observe a pink soild [ coppor metal] formed at the negative electrode in coppor sulfate solution.

A

Because ions are reduced and deposited.
Deposited - The process where a metal forms a solid layer on an electrode (the cathode) through the reduction of its ions.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Electrolysis

Why would bubbles form at the negative electrode in a sodium chloride solution?

A

Electricity passes through causing water to spilt into hydrogen and cholrine gas which causes bubbles forming at the electrode tip.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Electrolysis

What is the process of chemical cell?

A

Cells that are used in chemical reactions to produce electricity.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Electrolysis

What forms at the cathode?

What forms at the anode?

What is the general rule for
determining which anion is oxdized at the anode?

A

Metal
Non-metal
If the anion is halide ion it is oxidized at the anode.If the anion is not a halide ion, oxygen is produced at the anode.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Electrolysis

List the reactivity series.

A

Potassium
Sodium
Lithium
Calcium
Magnesium
Aluminium
Carbon’
Zinc
Iron
Hydrogen
Coppor
Silver
Gold

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Electrolysis

Some students investigated the electrolysis of copper nitrate solution using inert
electrodes.
The students investigated how the mass of copper produced at the negative
electrode varied with:
* time
* current
Some of the copper produced did not stick to the negative electrode but fell
to the bottom of the beaker.

Suggest how the students could find the total mass of copper produced [4]

A

Filter the mixture.[1]
Wash and dry the coppor to remove and residue.[1]
Weight the coppor collected.[1]
Add to incease in the mass of the electrode[1]

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Why is graphite used in electrodes? [2]

A

Graphite can conduct electricity.
It is unreactive.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Why is graphite unreactive?

A

Due to the carbon atoms which are bound in layers by strong covalent bonds, making it difficult to break down or react with other substances.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Electrolysis

What is an alloy?

A

A mixture of metals

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Electrolysis

What is the definition of crystallisation?

A

It is used to seperate soluable solid from a solution through evapouration of the solvent.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Electrolysis

Aluminium is produced by electrolysing a molten mixture of alminium oxide and cryolite.
Explain why a mixture is used as the electrolyte instead of using only alminium oxide?

A

Mixture has lower melting point than aluminium oxide.[1]
so less energy is needed[1]

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Electrolysis

1.What is cryolite and how is it used? [ state the chemical formuala]
2.Why is it used as a mixture as the electrolyte instead of using only aluminium oxide during the extraction of aluminium oxide? [2]

A

Cryolite is a white or colorless mineral with the chemical formula:
✅ Na₃AlF₆ → Sodium aluminum fluoride.
Cryolite is mixed with aluminum oxide, creating a mixture that acts as the electrolyte.

  1. Because it is a mixture that has lower melting point than aluminium oxide[1] so less energy is needed.[1]
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Electrolysis

Oxygen is produced at the postive electrode.
Explain why the postive electrode must be continually replaced?[3]

A

The electrode reacts with oxygen[1]
The electrodes are graphites[1] which is pure carbon.

so carbon dioxide is produced.[1]

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Electrolysis [ Textbook]

Why is aluminium extracted from the ore bauxite?

A

Because it contains aluminium oxide (Al₂O₃)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Reactivity of Metals

How do you calculate uncertainty?

A

(Largest value - smallest value)/2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Reactivity of Metals.

Tungsten (W) is a metal.
Tungsten is extracted from tungsten oxide (WO3).
All other solid products from the extraction method must be separated from
the tungsten.
The table below shows information about three possible methods to extract
tungsten from tungsten oxide.
Method
Reactant
Relative cost of
reactant
Products
(2)
(1)
(3)

1
Carbon
2
Hydrogen
Low
Tungsten solid
Carbon dioxide gas
Tungsten carbide
solid
High
3
Iron
Tungsten solid
Water vapour
Low
Tungsten solid Iron
oxide solid
Evaluate the three possible methods for extracting tungsten from tungsten
oxide.

Look at the key key word evaluate - pros and cons of each method.

Use terms like “most and least” if you have to. [4]

A

Carbon and iron are the cheapest reactant.[1]
However they need to seperate the solid products which is time-consuming.[1]
In method 2, the water vapour produced will escape [1]
There is no serperation of soild needed.[1]

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

Raectivity of Metals

As you go down Group 1 the reactivity increases, which means the electrons are further from the nucleus. How does that impact the reactivity of Group 1 metals? [2]

A

There is less attraction between nucleus and outer shell. [1]
so that atom loses an electron more easily.[1]

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

Reactivity of Metals

What is the shielding effect, and how does it affect electron loss? [2]

A

The shielding effect is when inner electron shells reduce the pull of the nucleus on the outer electron.
This makes the outer electron easier to lose.

19
Q

Reactivity of Metals

Why does a smaller atom hold onto its electrons more tightly? [1]

A

In smaller atoms, the outer electrons are closer to the nucleus, so the attraction is stronger, making it harder to lose electrons.[1]

20
Q

Reactivity of Metals

What is the structure of an ionic compund?[3]

A

It has a giant ionic lattice strcuture[1] the ions are closely packed in a regular lattice arrangement[1] and they have strong electrostatic forces of attraction between oppsoitely charged ions[1]

21
Q

Reactivity of Metals

Why are alloys harder than pure metal?[2]

A

Because they have different sized atoms[1] which means that the layers slide over each other less easily[1]

22
Q

Reactivity of Metals

Why is the temeprtaure change used to compare the reactivity of an unknown metal? [2]

A

The temperature change is a simple and reliable way to compare the energy released by different metals.

A larger temperature rise, the more reactive the metal.

23
Q

Reactivity of Metals

)
A student wants to compare the reactivity of an unknown metal, Q, with that
of zinc.
Both metals are more reactive than silver.
The student is provided with:
* silver nitrate solution
* metal Q powder
* zinc powder
* a thermometer
* normal laboratory equipment.
The metal is added to the silver nitate the solution.
Why is that? [1]
Describe the remaining steps the student could have done to compare the reactivity of metal
Q with that of zinc.
Your method should give valid results. [3]

A

To form silver metal during displacement reactions:

In reactions with a more reactive metal, the silver ions (Ag⁺) get displaced and form solid silver (Ag).[1]

Meausre the tempertaure change.[1]
when each metal is added to the silver nitrate solution.

The greater the temperature change, the more reactive the metal.[1]

The control variable is the same conecentartion of the solution.[1]

24
Q

Reactivity of metals

A student is given three metals X,Y and Z.
The metals are magensium, iron and coppor.
They are added in a dilute hydrochoric solution .
One of the results show copper as unreactive

Mention iron and magensium and the control variable.[2]

A

Magnesium produces bubbles faster than iron.[1]

The control variable is the same concentration of hydrochloric acid.[1]

25
# Reactivity of Metals Mention two differences of Group 1 metals and Group 2 metals?[2 marks]
Group 1 has lower density than transition metals. Group 1 has higher melting point.
26
# Reactivity of metals Why are ionic compounds soild at room temoerature.[2]
Because they have strong electrostatic forces pf attraction between oppsitely charged ions.[1] which means they need a lot of energy. [1]
27
# Reactions of Acids There is equiment that the student used to caluclate the titration of sulfuric acid and potassium hydroxide. Pour the potassium hyrdoxide solution into the conical flask. Add 2-3 drops of indicator and then use the funnel to fill the burette of sulfuric acid. State the remaing steps.
Until the colour of the indicator changes.[1] Read the volume of the burette. [1]
28
# Reactivity of the Acids A student makes crystals of magnesium sulfate. This is the method used. Add sulfuric acid to a beaker. Warm the sulfuric acid. Add a spatula of magnesium oxide to the beaker. Stir the mixture. Repeat steps 3 and 4 until there is magnesium oxide remaining in the beaker. Filter the mixture. Evaporate the filtrate gently until crystals start to form. Leave the solution to finish crystallising. Give one reason for: * step 2 * step 5 * step 6.
(Step 2) to speed up the reaction (Step 5) to make sure all the (hydrochloric) acid reacts (Step 6) to remove the excess magnesium oxide
29
# Reactivity of acids. What are the procducts of calcium hydroxide solution when it reacts with hydrocloric acid?
Calcium chloride and water.
30
# Reactivity of acids A student used a specific method to make pure, dry crystals of magensium sulfate to form a metal oxide and a dilute reaction. The student: Used sulfuric acid and magnesium oxide and added it to the beaker. They warmed the sulfuric acid using a water bath They added the magnesium oxide in excess using a spatula. Complete the steps
Filter the solution using filter paper and filter funnel to remove excess magnesium oxide. Heat the solution in an evapurating basin to crystalisation point. Dry the crystals using paper towel.
31
# Reactivity of acids What does it mean when an acid is fully ionised.
The acid completely breaks apart into hydrogen ions (H⁺) and the corresponding negative ions.
32
# Reactivity of acids What does the term dilute acid?
dilute acid means small amount of acid per unit volume
33
# Reactivity of acids What is the definition of filtration?
Filtration is used to separate an insoluble solid from a liquid
34
) A student added copper metal to colourless silver nitrate solution. The student observed: * pale grey crystals forming * the solution turning blue. Explain how these observations show that silver is less reactive than copper.
they have high melting points the (grey) crystals are silver the copper ions (produced) are blue (produced) is blue (because) copper displaces silver
35
A student is given three metals, X, Y and Z to identify. The metals are magnesium, iron and copper. Plan an investigation to identify the three metals by comparing their reactions with dilute hydrochloric acid. Your plan should give valid results
add the metals to (dilute) hydrochloric acid * measure temperature change compare rate of bubbling or compare colour of resulting solution for copper: * no reaction * shown by no temperature change or shown by no bubbles for magnesium and iron: * magnesium increases in temperature more than iron or magnesium bubbles faster than iron or magnesium forms a colourless solution and iron forms a coloured solution Control variables * same concentration / volume of hydrochloric acid * same mass / moles of metal * same particle size of metal * same temperature (of acid if compound]
36
# Electrolysis What is a fume cupboard?.[1]
To control and remove harmful vapors.[1]
37
What is electrolysis?[1]
The use of electricity to produce a chemical reactions.
38
The higher the concentration of a sample of dilute sulfuric acid, the greater the volume of sodium hydroxide needed to neutralise the acid. The student tested two samples of dilute sulfuric acid, P and Q. Describe how the student could use titrations to find which sample, P or Q, is more concentrated.[6]
measure the volume of acid * add indicator to the acid * add sodium hydroxide solution * until the colour changes * record volume of sodium hydroxide solution added * repeat procedure with the other acid Use of results * compare the two volumes of sodium hydroxide solution to find which sample P or Q is more concentrated Other points * pipette to measure volume of acid * use a few drops of indicator * swirl * use a white tile * rough titration to find approximate end point * add dropwise near the endpoint * read volume from bottom of m
39
Calcium nitrate contains the ions Ca2+ and NO3− Give the formula of calcium nitrate.
Ca(NO3)2
40
Describe a method to make pure, dry crystals of magnesium sulfate from a metal oxide and a dilute acid
use magnesium oxide and sulfuric acid * add sulfuric acid to a beaker * warm sulfuric acid * add magnesium oxide * stir * continue adding until magnesium oxide is in excess * filter * using a filter paper and funnel * to remove excess magnesium oxide * heat solution in an evaporating basin * to crystallisation point * leave to crystallise * pat dry with filter paper credit may be given for diagrams
41
his question is about acids and alkalis. (a) (b) Dilute hydrochloric acid is a strong acid. Explain why an acid can be described as both strong and dilute
(b) (c) (strong because) completely ionised (in aqueous solution) ignore pH allow dissociated for ionised do not accept hydrogen is ionising do not accept H+ are ionised (dilute because) small amount of acid per unit volume
42
Explain why the student should use a pipette to measure the dilute sulfuric acid and a burette to measure the sodium hydroxide solution. (
pipette measures a fixed volume (accurately) (but) burette measures variable volume
43
A student titrated citric acid with sodium hydroxide solution. This is the method used. 1. Pipette 25.0 cm3 of sodium hydroxide solution into a conical flask. 2. Add a few drops of thymol blue indicator to the sodium hydroxide solution. Thymol blue is blue in alkali and yellow in acid. 3. Add citric acid solution from a burette until the end-point was reached. (b) Explain what would happen at the end-point of this titration. Refer to the acid, the alkali and the indicator in your answer.
ndicator changes colour from blue to yellow allow from blue to green (when) the acid and alkali are (exactly) neutralised or (when) no excess of either acid or alkali
44