Chemical equations (Test for anions) Flashcards
The law of conservation of mass
states that the total mass of the products of a chemical reaction is the same as the total mass of the reactants
anion
a negative ion
Chloride test
- Add a few drops of AgNO3 solution to a solution of the solid.
- A white precipitate is formed which is soluble in dilute ammonia solution -> chloride
- Ag+ + Cl- -> AgCl
Sulfate or Sulfite
- Add BaCl2 solution to a solution of the solid.
- A white precipitate is formed.
- Ba2+ + SO4 2- -> BaSO4
Test to distinguish:
1. Add dilute HCl
2. If precipitate remains -> sulfate / If precipitate dissolves -> sulfite
3. BaSO4 + HCl -> no reaction / SO3 2- + 2H+ -> SO2 + H2O
Carbonate or Hydrogen - carbonate
- Add dilute HCl to the solid.
- Fizzing. A gas is given off that turns limewater milky.
- CO3 2- + 2H+ -> CO2 + H2O/ HCO3- + H+ -> CO2 + H2O / Ca(OH)2 + CO2 -> CaCO3 + H2O
Test to distinguish:
1. Add MgSO4 solution to a fresh solution of the solid.
2. White precipitate forms -> carbonate/ No precipitate forms -> hydrogencarbonate. Boiling gives a precipitate.
3. Mg2+ + CO3 2- -> MgCO3 / Mg2+ + 2HCO3- -> Mg(HCO3)2 / Mg(HCO3)2 -> MgCO3 + CO2 + H2O
Nitrate
- Brown ring test. To a solution of the solid add a freshly prepared FeSO4 solution. Add concentrated sulfuric acid.
- A brown ring is formed at the junction of the two liquids -> nitrate.
- Brown ring is due to presence of nitrate ion.
Phosphate
- Ammonium molybdate is added to a solution of the solid. Concentrated nitric acid is added. Solution is warmed.
- Yellow precipitate is formed -> phosphate.
- Phosphate ions are present.