Arrangement of electrons Flashcards
Bohr’s study of spectra
- Light passed through a glass prism and a series of narrow, coloured lines are observed.
- The emission spectrum of hydrogen consists of a series of lines of different colours. Each line corresponds to light of a different frequency.
Flame tests
- Use a damp wooden splint to hold a sample of each salt.
Lithium - Crimson (Crimson antidepressant)
Potassium - Lilac (Purple bananas)
Barium - Green (green oil)
Strontium - Red (red fireworks)
Copper - Blue-green (Blue-green tarnished ring from Shein)
Sodium - Yellow (Yellow chips)
Use of emission spectra
Sodium in street lamps (Gives yellow colour)
Gives colour to fireworks (when mix certain salts with certain metals)
The Bohr theory
- Electrons in an atom possess only a certain fixed amount of energy (quantum)
- Proposed that electros orbit the nucleus like planets in a solar system
An energy level
is defined as the fixed energy value that an electron in an atom may have
The ground state
of an atom is one in which the electrons occupy the lowest energy level available
The excited state
of an atom is one in which the electrons occupy the higher energy levels than those available in the ground state
Atomic absorption spectrometry
- Used to measure how much of a certain element is in a sample.
- Dark lines on a coloured spectrum when white light is passed through a sample in its gaseous state.
Principle behind the Atomic absorption spectrometry
- Atoms of an element in the ground state absorb light of a particular wavelength that is characteristic of the element.
- The amount of light absorbed by an element in solution is directly proportional to the concentration of the element.
Energy sublevels
- Energy transitions discovered when looking at emission spectra more closely, the lines produced from the emission spectra had smaller lines closer together.
- The number of energy sublevels is the same as the number of main energy levels i.e. in the 2nd energy level there are 2 sublevels, in the 3rd energy level there are 3 sublevels etc.
Energy sublevel
A group of atomic orbitals within an energy level, that all have the same energy.
Wave nature of an electron
If the electron has a wave motion, then it cannot be travelling in a precise path at a fixed distance from the nucleus.
Heinsenberg’s Uncertainty Principle
states that it is not possible to measure both the velocity and the position of an electron at the same time.
Limitations of Bohr’s Theory
- Only accounts for hydrogen atoms
- Does not take into account the wave nature of the electron
- Did not take into account the existence of sublevels
Atomic orbitals
A region of space surrounding the nucleus of an atom in which there is a high probability of finding an electron.