Chemical Equilibrium Flashcards

(34 cards)

1
Q

The reaction can be started from the reactant side only

A

IRREVERSIBLE REACTION

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2
Q

Only the forward reaction takes place

A

IRREVERSIBLE REACTION

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3
Q

Represented by a normal arrow

A

IRREVERSIBLE REACTION

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4
Q

The reaction proceeds to completion

A

IRREVERSIBLE REACTION

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5
Q

The reaction can be started from either side

A

REVERSIBLE REACTION

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6
Q

Forward and backward reactions are in equilibrium

A

REVERSIBLE REACTION

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7
Q

Represented by an equilibrium arrow

A

REVERSIBLE REACTION

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8
Q

The reaction is never complete

A

REVERSIBLE REACTION

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9
Q

Properties such as concentrations of reactants and products, pressure and color are ___________.

A

constant

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10
Q

A system in equilibrium is a ____________ system

A

Closed

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11
Q

The rate of the forward reaction equals the rate of the ___________ reaction

A

reverse

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12
Q

Equilibrium can be approached from the _______________ or ______________ direction and the final equilibrium position is the same

A

forward or reverse

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13
Q

Involves reactants and
products that are
present in one phase

A

Homogeneous

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14
Q

Involves reactants and
products that are
present in different
phase

A

Heterogeneous

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15
Q

True or False
aA + bB ⇌ cC + dD

The equilibrium constant for this reaction is defined as the ratio of the concentrations (partial pressures) of the products divided by the concentration (partial pressures) of the reactants, at equilibrium, raised to their stoichiometric coefficients.

A

True

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16
Q

Kc
The symbol c in Kc indicates that the units for the reactants and products are those of ______________.

A

molar concentration

17
Q

Kp
For reactions involving gases, the equilibrium constant is often expressed in terms of __________________________ rather than their concentrations.

A

partial pressures

18
Q

In writing equilibrium, constant expression for heterogeneous reactions involving gases and a solid or a liquid, the concentration of pure liquids and pure solids are ____________________ because they have constant concentrations.

19
Q

can be used to measure the extent of a
chemical reaction. This quantity
is also used to determine how
far from equilibrium the chemical
reaction is.

A

REACTION QUOTIENT

20
Q

Q < K

What direction?

A

Favors the forward direction

21
Q

Q = K

What direction?

22
Q

Q > K

What direction?

A

Favors the reverse direction

23
Q

What Law?

If a chemical system at
equilibrium is disturbed or
stressed, the system will react in
the direction that counteracts the
disturbance or relieves the
stress.

A

LE CHATELIER’S PRINCIPLE

24
Q

Addition of reactant drives
the equilibrium to the ______

25
Addition of product drives the equilibrium to the ______
left
26
Adding more reactants Favors the __________ reaction
forward
27
Adding more products Favors the ________ reaction
reverse
28
Removing a reactants Favors the ___________ reaction
reverse
29
Removing a product Favors the ____________ reaction
forward
30
The reaction can be shifted forward or backward by changing the ______________.
pressure
31
Decrease the number of moles to decrease ______________
pressure
32
Increase in pressure Equilibrium favors the side that has ____________ moles
fewer
33
Decrease in pressure Equilibrium favors the side that has __________ moles
more
34
increases the rate of chemical reactions. It increases the rate of the forward reaction as well as the backward reaction to the same extent.
CATALYST