chemical equilibrium Flashcards

1
Q

when equilibrium lies to the right-

A

more products than reactants, -G forward

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

when equilibrium lies to the left-

A

more reactants than products, +G forwards

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

K<1

A

lies left

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

K>1

A

lies right

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

K (and Q) expression

A

K= products/ reactants

NO SOLIDS OR LIQUIDS

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Manipulation of k expression

A

1) reversal
K=1/K

2) Multiplying
K=K^n

3) Dividing
K=K^r/n

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what does RICE stand for

A

Reaction, initial, change, equilibrium

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Right shift

A

reactants decrease, K>Q

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

left shift

A

Reactants increase, K<Q

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

equation for delta G

A

G=-RT ln K

(R=8.314 J/k*mol)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

shift when increasing reactant molarity

A

right

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

shift when decreasing reactanr molarity

A

lefy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

shift when increasing product molarity

A

left

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

shift when decreasing product molarity

A

right

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

+H

A

Endothermic, heat is a reactant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

-H

A

exothermic, heat is a product

17
Q

shift when increasing +H temp

A

right

18
Q

shift when decreasing +H temp

A

left

19
Q

shift when increasing -H temp

A

left

20
Q

shift when decreasing -H temp

A

right

21
Q

shift when increasing pressure with noble gas

A

no shift

22
Q

increase pressure by reducing volume

A

away from side with more moles of gas

23
Q

decrease pressure by increasing volume

A

towards side with more moles of gas