Chemical tests Flashcards

Learn all of the chemical tests for ions and functional groups. (46 cards)

1
Q

What is tollens reagent use to test for

A

aldehydes

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2
Q

What is bromine water used to test for

A

alkenes ( Electrophilic addition occurs)

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3
Q

how do you carry out a flame test

A

dip a nicrome wire in hydrochloric acid then dip it in the unknown compound and hold it over a bunson burner

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4
Q

which silver halides dissolve in concentrated ammonia

A

silver chloride and silver iodide

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5
Q

write an equation for the white precipitate formed when using barium ions to test for sulfide ions

A

Ba^2+(aq) + SO4^2+(aq) =) BaSO4(s)

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6
Q

what colour change will indicate a positive result when using bromine water to test for alkenes

A

the solution should go from orange to colourless

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7
Q

What conditions are needed when using fehilings solution to test for aldehydes

A

you need to heat the solution

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8
Q

what can be used to test for carboxylic acids

A

Solid sodium carbonate

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9
Q

How do you test for carbonate ions

A

you add dilute hydrochloric acid ( or any acid)

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10
Q

what factor of hydroxide ions is their chemical test bassed on

A

the fact that they make solutions alkaline

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11
Q

if ammonia is present what colourchange wil be observed on the damp red litmous paper

A

the paper will turn from red to blue

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12
Q

which silver hialides dissolve in dilute ammonia

A

silver chloride

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13
Q

what colour precipitate does bromide give when testing for halide ions

A

A cream precipitate ( of silver bromide)

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14
Q

what is solid sodium carbonate used to test for

A

carboxylic acids

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15
Q

write an equation for how the silver mirror is formed when tollens reagent is mixed with an aldehyde to form a silver mirror

A

Ag+(aq) + e- =) Ag(s)

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16
Q

What does a solution turning from orange to green in acidified potassium dichromate indicate

A

a primary and/or secondary alcohol is present

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17
Q

what is it important to do when using bromine water to test for alkenes

A

shake the test tube

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18
Q

what colour change will indicate a positive resut for fehlings solution

A

a blue solution to a brick red precipitate

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19
Q

when tollings solution is mixed with an aldehyde what colour change is observed

A

the solution will go from colourless to form a silver mirror

20
Q

write an equation to show how potassium dichromate is oxidised when mixed with a primary or secondary alcohol

A

Cr2O7 + 6e- =) 2Cr^3+ + 7H2O

21
Q

in a flame test what colour does barium (Ba^2+) burn

22
Q

What reagent is used to test for primary and secondary alcohols. (HINT: it acts as a reducing agent)

A

Potassium dichromate (VI)

23
Q

in a flame test what colour does calcium (Cu^2+) burn

24
Q

how can you test for ammonium ions

A

using damp red litmous paper

25
how do you test for sulfide ions
you add dilute hydrochloric acid followed by barium chloride solution
26
how do you test for hydroxide ions
using a PH indicatior for example using red litmous paper if the ions are present the paper will go from red to blue
27
What colour precipitate des iodide give when testing for halide ions
a yellow precipitate (of silver iodide)
28
what do you need to do when using red litmious paper to test for ammonium ions
you need to add sodium hydroxide to produce ammonia: | NH4+ + OH- =) NH3 + H2O
29
what indicates a positive result when adding hydrochloric acid to a solution to test for carbonate ions
the carbonate ions will fizz because CO2 is being produced. It will also turn lime water cloudy
30
What can be used to test for alkenes
bromine water
31
What can be used to test for aldehydes
Fehlings or benidicts solution (they oxidise aldehydes but not ketones) or tollings reagent
32
what indicates a positive result when solid sodium carbonate is mixed with a carboxylic acid
The solution will fizz | if bubbled through limewater in a second test tube it will turn it cloudy (CO2 is produced)
33
How do you test for halide ions (chloride, bromide and iodide)
add dilute nitric acid (HNO3) | followed by silver nitrate (AgNO3)
34
how do you prepare tollings reagent
you mix silver nitrate and dilute sodium hydroxide then add drops of ammonia solution
35
write an equation fot the reacton of the carbonate ions with the hydrogen ions when using hydrochloric acid to test for caronate ions
CO3^2-(aq) + 2H+ =) CO2(g) + H2O(l)
36
colour precipitate does chroride give when testing for halide ions
a white precipitate ( of silver chloride)
37
what will be observed when a positive result comes from a test with potassium dichromate to test from primary and secondary alcohols
it turns from an orange solution to a green solution
38
what are flame tests used to identify
group 2 metals
39
in benedicts solution what are the copper ions dissolved in
sodium carbonate
40
in feilings solution what are the copper ions desolved in
sodium hydroxide
41
What other conditions are needed when using potassium dichromate to test for primary and secondary alcohols
Acidified and heat
42
what does a solution turning brick red (from blue) in fehlings or benidicts indicate ?
an aldehyde is present
43
in a flame test what colour does strontium (Sr^2+) burn
red
44
when using dilute hydrochloric acid and barium chloride solution to test for sulfide ions what indicates a positive result
a white precipitate will form
45
write an equation to show how the copper ions in fehlings solution are oxidised when mixed with an aldehydes
Cu^2+ +2OH- + 2e- =) Cu2O + H2O
46
How do you distinguish between primary and secondary alcohols
- oxidise an alcohol under reflux then test for carboxylic acids - oxidse an alcohol under distillation then test for an aldehyde - oxidise an alcohol under reflux then test for a keytone