CHEMISTRY 2: Stoichiometry, Chemical Bonds Flashcards

(37 cards)

1
Q

Is the study of quantitative aspects of chemical formulas and chemical reaction

A

Stoichiometry

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2
Q

Amount of any substance that contains the same number of elementary entities as there are atoms in 12g of 12c

A

Mole

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3
Q

Is the mass per mole of entities (atoms, molecules or formula units)

A

Molar Mass

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4
Q

Familiarize stoich map

A

GO NAAA

Mass → Mole = Mass/Molar Mass
Particles→ mole = Atoms/Avogadro’s number

Mol → Mass = Mol x Molar Mass
Mol → Particle = Mol x Avogadro’s number

palabas ang times, paloob divide (arrow)

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5
Q

→ Is the quantitative relationship between the amounts of reactants used and amounts of products formed in a reation

→Expressed in balanced equationExpressed in balanced equation

A

Chemical Stoichiometry

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6
Q

Formula of Percent Yield?

A

% yield = Actual yield/Theoretical yield (100)

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7
Q

→ The amount of product that could possibly be produced in a given reaction

→ Calculated according to the starting amount

A

Theoretical yield

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8
Q

→ The amount of product actually obtaiend in a chemical reaction

A

Actual yield

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9
Q

→ A chemical reactant that limits the amount of product that is formed

A

Limiting reactant

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10
Q

→ Gives smallest yield of product calculated from the reagents available

A

Limiting agent

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11
Q

→ Is the reactant in a chemical reaction with a greater amount than necessary to react completely with the limiting reactant

A

Excess reactant

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12
Q

Formula and Composition

Shows the simplest ratio of elements in a molecular compound

A

Empirical formula

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13
Q

Shows the number and type of atoms that make up a molecule

A

Molecular formula

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14
Q

Atoms combine, electron distribution changes

A

Chemical Bonds

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15
Q

What are the 3 types of chemical bonds?

A
  1. Covalent bond
  2. Ionic bond
  3. Metallic bond
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16
Q

3 types of chemical bonds

Results from shairng of electrons between atoms. Found between nonmetals

A

Covalent bonding

18
Q

3 types of chemical bonds

Results from transfer of electrons from a metal to a non metal

A

Ionic bonding

19
Q

3 types of chemical bonds

Outer electrons move throughout solid and holds nuclei together and the compound is only composed of metals

A

Metallic bond

20
Q

Allows us to draw shape of a molecule which helps us to understand its properties

A

Lewis Structure

21
Q

→ Some atom atomd in the third row of the periodic table and beyond can acommodate 4 paiard of electrons

→ Termed a central atom and the atoms bonded to it are called outer atoms

A

Hypervalent Atoms

22
Q

→ A tool used to represent certain types of molecular structures

→ Arises when no single conventional model using only single double or triple bond can account for all the observed properties of the molecule

23
Q

→ Used to evaluate non-equivalent Lewis structures

→ no. of valence electron in free state -no. of nonbonding electrons - no. of bonds

A

Formal charge

24
Q

Is a set of empirical rules for predicting a molecular geometry using, as input, a correct lewis dot representation

A

Valence Shell Electron Pair Repulsion (VSEPR)

25
Distribution of regions of high electron density around the central atom
Electronic geometry
26
Arrangement of atoms around the central atom
Molecular geometry
27
T or F If lone pairs are present, molecular and electronic geometries are samae
F (they are different, same if no lone pairs are present)
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Dipole momements for all bonds cancel out
Nonpolar molecule
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Dipole moments for all bonds don't cancel out/ has net dipole moment
Polar molecule
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→ Is the force that holds molecules together →A form of "stickiness" between molecules
Intermolecular Force of Attraction (IMFA)
31
What are the 4 types of Intermolecular Forces of Attraction
1. London Dispersion Forces 2. Dipole-dipole forces 3. Hydrogen bonding 4. Ion-Dipole Forces
32
# 4 Types of Intermolecular Forces of Attraction → Called "Induced dipole forces or dispersion forces" → Temporary dipole attraction between non polar molecules that form due to shifting electrons → Electrons concentrate in one region, which results in temporary dipole that disappears when the electrons shift again → Temporary **partially negative charge and partially positive** charge forms
London Dispersion Forces | only type of IMF between nonpolar molecules (weakest since temporary)
33
Familiarize the the process of London Dispersion Forces
1.Temporary dipole appears when electrons shift within one of the nucleus 2.Adjacent molecule will be attracted to the molecule with temporary dipole and a new dipole within the second molecule will be induced 3.Electrons move back and temporary dipole disappears
34
# 4 Types of Intermolecular Forces of Attraction → A permanent dipole force exists between polar molecules →Attraction form between the partially positive and partially negative ends of adjacent polar molecules
Dipole-dipole forces | Stronger than london dispersion forces since these are permanent ## Footnote only polar molecules can form dipole-dipole
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# 4 Types of Intermolecular Forces of Attraction → Strong dipole force exists between molecules containing** H-F, H-O or H-N** bonds (high polar due to large electronegativity difference)
Hydrogen bonding | very strong type of IMF between polar molecules
36
# 4 Types of Intermolecular Forces of Attraction → When an ionic compound such as NaCl dissolves in water, the water molecules arrange their oppositely charged dipole to be attracted to fully charged ion creating a very strong attractive force
Ion-Dipole Forces
37