Chemistry Chapters 3-4 Flashcards

(58 cards)

1
Q

What is required for electrical conductivity?

A

The presence of ions in solution.

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2
Q

What are cations?

A

Metal ions

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3
Q

What are anions?

A

Non-metal ions

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4
Q

What are salts?

A

Ionic compounds

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5
Q

What are molecular compounds?

A

Compounds made up of non-metal atoms and do not form ions, therefore do not conduct electricity

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6
Q

True or false: some molecular compounds can form ions

A

true

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7
Q

What is a molecular solution?

A

Consists of one or more polar covalent compound that will mix with water (ex: ethanol in water, no dissociation)

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8
Q

What is an ionic solution?

A

Consists of one or more ionic compounds dissolved in water (ex: NaCl dissolved in water, dissociation occurs and conducts electricity)

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9
Q

What happens when an ionic compound dissolves in water?

A

The water molecules attract and separate the anions and cations in the solute.

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10
Q

What is dissociation?

A

The process of separating positive and negative ions in solution. (dissociation equations)

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11
Q

True or False: all ionic solutions dissolve at the same rate

A

false

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12
Q

What is the concentration of ions when a solute is dissolving in water?

A

proportional to the concentration of solution formed (according to coefficients)

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13
Q

How do you make a solution?

A

Dissolve some solute in solvent

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14
Q

What is a saturated solution?

A

When no more solid will dissolve (there must be undissolved solid present)

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15
Q

What happens when a precipitate is formed in a saturated solution?

A

The solution is saturated with the ions that form the precipitate.

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16
Q

What is solubility?

A

The amount of solute required to make a certain volume of saturated solution (the max amount that can be dissolved in a particular volume of solution)

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17
Q

True or false: Acids are soluble

A

True

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18
Q

When do salts usually have low solubility?

A

when they contain phosphates, sulphites, and carbonates

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19
Q

Give an example of a balanced equation

A

2KI(aq) + Pb(NO3)2 single arrow 2KNO3 (aq) + PbI2(s)

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20
Q

Give an example of a complete ionic equation

A

2K+ 2I-… (include phases, do not split up the precipitate but still include it)

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21
Q

Give an example of a net ionic equation

A

Pb2+(aq) + 2I-(aq) single arrow PbI2(s) (only the ions involved in the reaction, others are called spectators)

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22
Q

What is hard water caused by?

A

the pressure of metal ions such as Ca2+ and Mg2+, the ions react with soap and inhibit their function

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23
Q

What type of water is most likely to be hard?

A

slow-moving ground water has more time for the ions to dissolve

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24
Q

How can you soften water

A

Add washing soda (NaCO3) to precipitate the metal ions

25
Where does equilibrium exist in solutions, describe them
Between the undissolved solid and dissolved ions -dissolved compound always on the left and is solid, ions on the right side and aqueous -double arrows
26
Where is equilibrium established in a saturated solution?
Between the dissolving and recrystallization of a salt
27
What does Ksp stand for?
Solubility product constant
28
What does the Ksp value represent?
High Ksp usually means high solubility, vice versa
29
What happens to the concentration of ions and Ksp if the solubility of the substance increases?
they both increase
30
True or false: ionic compounds with low solubility will not have Ksp values
false
31
With trial Ksp in mind, when will a precipitate form?
when trial Ksp > Ksp
32
What are operational definitions, give an example
Described physically what acids and bases do Ex: bases turn red litmus paper blue, acids react with magnesium
33
What are conceptual definitions, give an example
Define acids or bases in terms of their molecular structure ex: acids contain H+, bases have OH-
34
Give the Arrhenius definition of an acid
A substance that produces H+ in solution
35
Give the Arrhenius definition of a base
A substance that produces OH- in solution
36
What will happen when you place an acid with a strong base (an alkali metal with an OH-)?
The base will reduce all protons, acid + base = water + salt
37
List some characteristics of acids
-sour taste -react with metals to produce H2 -conduct electricity
38
List some characteristics of bases
-bitter taste -feel slippery/soapy -conduct electricity
39
Give the Bronsted Lowry definition of an acid
Any substance that can dissociate or donate a hydrogen ion (H+ or protein) eg: HCl = H+ + Cl-
40
Give the Bronsted Lowry definition of a base
Any substance that can accept a proton eg: OH- + H+ = H2O
41
What is an amphiprotic substance?
A substance that can act as either an acid or a base depending on the situation (not at the same time) ex: H2O
42
What are conjugate acid/base pairs
2 substances that only differ by one proton eg: NH3 and NH4+ a bronsted lowry acid base reaction always has 2 conjugate acid/base pairs
43
What is a polyprotic substance?
An acid or base capable of donating or excepting more than one proton ex: H3PO4
44
What is a strong acid?
-A substance that completely ionizes in an aqueous solution ex: HCl -dissociate completely in solution -single arrows
45
What is a weak acid?
A substance that only partially ionizes in an aqueous solution -they reach equilibrium and do not dissociate completely -double arrows
46
True or false: concentrated weak acids become strong acids
false, concentration has nothing to do with strong or weak acids
47
What is a strong base?
a substance that completely dissociates in aqueous solutions ex: oxides (NaOH, KOH)
48
What is a weak base?
a substance that produces few ions in solution ex: (nitrogen) NH3
49
What is Ka and Kb?
Acid ionization constant and base ionization constant
50
What does a large Ka or Kb indicate?
The acid or base is strong
51
How can you see if the forward or reverse reaction is favoured from an acid base equilibrium?
comparing the Ka values of the 2 acids, the higher Ka value is the favoured direction (exception: if an acid has no charge, its direction will be favoured)
52
Is pure water acidic or basic?
Neither, it is neutral!
53
What is Kw?
[H3O+][OH-]
54
What is autoionization?
When one water molecule donates a proton to another water molecule in a bronsted lowry equilibrium
55
What 2 factors must be considered when reacting strong acids with strong bases?
1. Solutions will dilute each other (V1M1 = V2M2) 2. Acids and bases will neutralize each other (the resulting solution will be acidic or basic depending on what is left over)
56
What is the formula for ph?
-log(H3O+) the amount of sig figs in the concentration will be the amount of decimal places
57
How to get (H3O+) from ph?
10^-ph the amount of decimal places will be the number of sig figs
58
True or false: there are different formulas for pOH and (OH-)
false, the formulas and rounding are the same